Flexible Route to [4.1.1] Propellanes

Ahmad Al-Dulayymi; Juma'a Al-Dulayymi; Mark Baird

Flexible Route to [4.1.1] Propellanes

Ahmad Al-Dulayymi
, Juma'a Al-Dulayymi
, Mark Baird

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

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Reaction of Diels-Alder adducts of 1-bromo-2-bromomethylcyclopropene and either 1,3-dienes or furans with butyl lithium leads to a 1,3-dehalogenation to produce [4.1.1]propellanes. The oxygen bridged propellane derived from furan reacts with a second mol.equiv. of butyllithium by cleavage of the bridge with allylic rearrangement and the formation of a cis-3-butyl-[4.1.1]propell-4-en-2-ol.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	6755-6758
Cyfnodolyn	Tetrahedron Letters
Cyfrol	38
Rhif cyhoeddi	38
Statws	Cyhoeddwyd - 1997

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@article{6911d95536c94d1a91d4084b3606437d,

title = "Flexible Route to [4.1.1] Propellanes",

abstract = "Reaction of Diels-Alder adducts of 1-bromo-2-bromomethylcyclopropene and either 1,3-dienes or furans with butyl lithium leads to a 1,3-dehalogenation to produce [4.1.1]propellanes. The oxygen bridged propellane derived from furan reacts with a second mol.equiv. of butyllithium by cleavage of the bridge with allylic rearrangement and the formation of a cis-3-butyl-[4.1.1]propell-4-en-2-ol.",

author = "Ahmad Al-Dulayymi and Juma'a Al-Dulayymi and Mark Baird",

year = "1997",

language = "English",

volume = "38",

pages = "6755--6758",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "38",

}

TY - JOUR

T1 - Flexible Route to [4.1.1] Propellanes

AU - Al-Dulayymi, Ahmad

AU - Al-Dulayymi, Juma'a

AU - Baird, Mark

PY - 1997

Y1 - 1997

N2 - Reaction of Diels-Alder adducts of 1-bromo-2-bromomethylcyclopropene and either 1,3-dienes or furans with butyl lithium leads to a 1,3-dehalogenation to produce [4.1.1]propellanes. The oxygen bridged propellane derived from furan reacts with a second mol.equiv. of butyllithium by cleavage of the bridge with allylic rearrangement and the formation of a cis-3-butyl-[4.1.1]propell-4-en-2-ol.

AB - Reaction of Diels-Alder adducts of 1-bromo-2-bromomethylcyclopropene and either 1,3-dienes or furans with butyl lithium leads to a 1,3-dehalogenation to produce [4.1.1]propellanes. The oxygen bridged propellane derived from furan reacts with a second mol.equiv. of butyllithium by cleavage of the bridge with allylic rearrangement and the formation of a cis-3-butyl-[4.1.1]propell-4-en-2-ol.

M3 - Article

SN - 0040-4039

VL - 38

SP - 6755

EP - 6758

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 38

ER -

Flexible Route to [4.1.1] Propellanes

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