Polyborate anions templated by cationic transition-metal complexes:: [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75 H2O

Mohammed Altahan; Michael Beckett; Simon J. Coles; Peter N. Horton

doi:10.1080/10426507.2015.1128907

Polyborate anions templated by cationic transition-metal complexes: [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75 H2O

Mohammed Altahan
, Michael Beckett
, Simon J. Coles
, Peter N. Horton

University of Southampton

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

304 Wedi eu Llwytho i Lawr (Pure)

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The transition metal complexes [Co(diNOsar)]3+, [Co(en)3]3+, and [Co(dien)2]3+ have been used to template unusual isolated polyborate anions by reaction of basic aqueous solutions containing the cations with B(OH)3 (1:10). The synthesis and characterization (thermal gravimetric analysis/differential scanning calorimetry, infrared spectroscopy, nuclear magnetic resonance, and single-crystal X-ray diffraction) of one such complex [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75H2O (1) is reported. Compound 1 is a rare example of a salt containing the isolated triborate(1-) anion, and its formation is engineered by the cation, which has extensive H-bond interactions with the anion in its secondary coordination sphere.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	572-575
Cyfnodolyn	Phosphorus, Sulfur and Silicon and the Related Elements
Cyfrol	191
Rhif cyhoeddi	4
Dyddiad ar-lein cynnar	6 Chwef 2016
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1080/10426507.2015.1128907
Statws	Cyhoeddwyd - 1 Ebr 2016

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10.1080/10426507.2015.1128907

PS Si 2016 vol 191 p572Llawysgrif awdur wedi’i dderbyn, 689 KB

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title = "Polyborate anions templated by cationic transition-metal complexes:: [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75 H2O",

abstract = "The transition metal complexes [Co(diNOsar)]3+, [Co(en)3]3+, and [Co(dien)2]3+ have been used to template unusual isolated polyborate anions by reaction of basic aqueous solutions containing the cations with B(OH)3 (1:10). The synthesis and characterization (thermal gravimetric analysis/differential scanning calorimetry, infrared spectroscopy, nuclear magnetic resonance, and single-crystal X-ray diffraction) of one such complex [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75H2O (1) is reported. Compound 1 is a rare example of a salt containing the isolated triborate(1-) anion, and its formation is engineered by the cation, which has extensive H-bond interactions with the anion in its secondary coordination sphere.",

keywords = " Triborate(1-), self-assembly, H-bonds, [Co(diNOsar)]3+, X-ray structure, oxidoborate",

author = "Mohammed Altahan and Michael Beckett and Coles, \{Simon J.\} and Horton, \{Peter N.\}",

year = "2016",

month = apr,

day = "1",

doi = "10.1080/10426507.2015.1128907",

language = "English",

volume = "191",

pages = "572--575",

journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

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T1 - Polyborate anions templated by cationic transition-metal complexes:

T2 - [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75 H2O

AU - Altahan, Mohammed

AU - Beckett, Michael

AU - Coles, Simon J.

AU - Horton, Peter N.

PY - 2016/4/1

Y1 - 2016/4/1

N2 - The transition metal complexes [Co(diNOsar)]3+, [Co(en)3]3+, and [Co(dien)2]3+ have been used to template unusual isolated polyborate anions by reaction of basic aqueous solutions containing the cations with B(OH)3 (1:10). The synthesis and characterization (thermal gravimetric analysis/differential scanning calorimetry, infrared spectroscopy, nuclear magnetic resonance, and single-crystal X-ray diffraction) of one such complex [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75H2O (1) is reported. Compound 1 is a rare example of a salt containing the isolated triborate(1-) anion, and its formation is engineered by the cation, which has extensive H-bond interactions with the anion in its secondary coordination sphere.

AB - The transition metal complexes [Co(diNOsar)]3+, [Co(en)3]3+, and [Co(dien)2]3+ have been used to template unusual isolated polyborate anions by reaction of basic aqueous solutions containing the cations with B(OH)3 (1:10). The synthesis and characterization (thermal gravimetric analysis/differential scanning calorimetry, infrared spectroscopy, nuclear magnetic resonance, and single-crystal X-ray diffraction) of one such complex [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75H2O (1) is reported. Compound 1 is a rare example of a salt containing the isolated triborate(1-) anion, and its formation is engineered by the cation, which has extensive H-bond interactions with the anion in its secondary coordination sphere.

KW - Triborate(1-), self-assembly, H-bonds, [Co(diNOsar)]3+, X-ray structure, oxidoborate

U2 - 10.1080/10426507.2015.1128907

DO - 10.1080/10426507.2015.1128907

M3 - Article

SN - 1042-6507

VL - 191

SP - 572

EP - 575

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

IS - 4

ER -

Polyborate anions templated by cationic transition-metal complexes: [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75 H2O

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