Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system

A. Charlton; D. Donati; S. Fusi; P.J. Murphy; F. Ponticelli

doi:10.1016/j.tetlet.2012.12.080

Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system

A. Charlton
, D. Donati
, S. Fusi
, P.J. Murphy
, F. Ponticelli

Prifysgol Bangor

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

217 Wedi eu Llwytho i Lawr (Pure)

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Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	1227-1229
Cyfnodolyn	Tetrahedron Letters
Cyfrol	54
Rhif cyhoeddi	10
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1016/j.tetlet.2012.12.080
Statws	Cyhoeddwyd - 6 Maw 2013

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10.1016/j.tetlet.2012.12.080

TL 2013Llawysgrif awdur wedi’i dderbyn, 461 KBTrwydded: CC BY-NC-ND

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@article{d20195191bb44ba9b6605a361eb6f8b1,

title = "Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system",

abstract = "Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.",

author = "A. Charlton and D. Donati and S. Fusi and P.J. Murphy and F. Ponticelli",

note = "The work was financially supported by the PRIN Project 2009",

year = "2013",

month = mar,

day = "6",

doi = "10.1016/j.tetlet.2012.12.080",

language = "English",

volume = "54",

pages = "1227--1229",

journal = "Tetrahedron Letters",

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number = "10",

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TY - JOUR

T1 - Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system

AU - Charlton, A.

AU - Donati, D.

AU - Fusi, S.

AU - Murphy, P.J.

AU - Ponticelli, F.

N1 - The work was financially supported by the PRIN Project 2009

PY - 2013/3/6

Y1 - 2013/3/6

N2 - Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.

AB - Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.

U2 - 10.1016/j.tetlet.2012.12.080

DO - 10.1016/j.tetlet.2012.12.080

M3 - Article

SN - 0040-4039

VL - 54

SP - 1227

EP - 1229

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 10

ER -

Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system

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