Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene

A. Kreuziger; M.A. Beckett; P.N. Horton; S.J. Coles; D.A. Kose; A.M. Kreuziger

doi:10.1016/j.poly.2012.02.031

Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene

A. Kreuziger
, M.A. Beckett
, P.N. Horton
, S.J. Coles
, D.A. Kose
, A.M. Kreuziger

Engineering and Physical Sciences Research Council (EPSRC)

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

Crynodeb

The reaction of the cyclic amines 1,5-diazobicyclo[4.3.0]non-5-ene (DBN), 1,8-diazobicyclo[5.4.0]undec-7-ene (DBU) and 1,8-bis(dimethylamino)naphthalene (PS) with B(OH)3 in a 1:5 ratio affords in high yields the non-metal cation pentaborate salts [HDBN][B5O6(OH)4] (1), [HDBU][B5O6(OH)4] (2) and [HPS][B5O6(OH)4]·B(OH)3 (3). Compounds 1–3 were characterized by spectroscopic studies (NMR, IR) and compounds 1 and 3 were further characterized by single-crystal XRD studies. The pentaborate salts compounds show extensively H-bonded supramolecular anionic lattices which are templated by the cations. Thermal analysis (TGA) of 1–3 showed that thermally decomposed in air at 1000° to B2O3 in a two step process involving dehydration (

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	157-161
Cyfnodolyn	Polyhedron
Cyfrol	38
Rhif cyhoeddi	1
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1016/j.poly.2012.02.031
Statws	Cyhoeddwyd - 17 Maw 2012

Mynediad at Ddogfen

10.1016/j.poly.2012.02.031

Ôl bys

Gweld gwybodaeth am bynciau ymchwil 'Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene'. Gyda’i gilydd, maen nhw’n ffurfio ôl bys unigryw.

Dyfynnu hyn

Kreuziger, A., Beckett, M. A., Horton, P. N., Coles, S. J., Kose, D. A., & Kreuziger, A. M. (2012). Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene. Polyhedron, 38(1), 157-161. https://doi.org/10.1016/j.poly.2012.02.031

@article{71cec298447e4b5398b4d1f2ab16b6e7,

title = "Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene",

abstract = "The reaction of the cyclic amines 1,5-diazobicyclo[4.3.0]non-5-ene (DBN), 1,8-diazobicyclo[5.4.0]undec-7-ene (DBU) and 1,8-bis(dimethylamino)naphthalene (PS) with B(OH)3 in a 1:5 ratio affords in high yields the non-metal cation pentaborate salts [HDBN][B5O6(OH)4] (1), [HDBU][B5O6(OH)4] (2) and [HPS][B5O6(OH)4]·B(OH)3 (3). Compounds 1–3 were characterized by spectroscopic studies (NMR, IR) and compounds 1 and 3 were further characterized by single-crystal XRD studies. The pentaborate salts compounds show extensively H-bonded supramolecular anionic lattices which are templated by the cations. Thermal analysis (TGA) of 1–3 showed that thermally decomposed in air at 1000° to B2O3 in a two step process involving dehydration (",

author = "A. Kreuziger and M.A. Beckett and P.N. Horton and S.J. Coles and D.A. Kose and A.M. Kreuziger",

year = "2012",

month = mar,

day = "17",

doi = "10.1016/j.poly.2012.02.031",

language = "English",

volume = "38",

pages = "157--161",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "1",

}

Kreuziger, A, Beckett, MA, Horton, PN, Coles, SJ, Kose, DA & Kreuziger, AM 2012, 'Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene', Polyhedron, cyfrol. 38, rhif 1, tt. 157-161. https://doi.org/10.1016/j.poly.2012.02.031

Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene. / Kreuziger, A.; Beckett, M.A.; Horton, P.N. et al.
Yn: Polyhedron, Cyfrol 38, Rhif 1, 17.03.2012, t. 157-161.

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

TY - JOUR

T1 - Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene

AU - Kreuziger, A.

AU - Beckett, M.A.

AU - Horton, P.N.

AU - Coles, S.J.

AU - Kose, D.A.

AU - Kreuziger, A.M.

PY - 2012/3/17

Y1 - 2012/3/17

N2 - The reaction of the cyclic amines 1,5-diazobicyclo[4.3.0]non-5-ene (DBN), 1,8-diazobicyclo[5.4.0]undec-7-ene (DBU) and 1,8-bis(dimethylamino)naphthalene (PS) with B(OH)3 in a 1:5 ratio affords in high yields the non-metal cation pentaborate salts [HDBN][B5O6(OH)4] (1), [HDBU][B5O6(OH)4] (2) and [HPS][B5O6(OH)4]·B(OH)3 (3). Compounds 1–3 were characterized by spectroscopic studies (NMR, IR) and compounds 1 and 3 were further characterized by single-crystal XRD studies. The pentaborate salts compounds show extensively H-bonded supramolecular anionic lattices which are templated by the cations. Thermal analysis (TGA) of 1–3 showed that thermally decomposed in air at 1000° to B2O3 in a two step process involving dehydration (

AB - The reaction of the cyclic amines 1,5-diazobicyclo[4.3.0]non-5-ene (DBN), 1,8-diazobicyclo[5.4.0]undec-7-ene (DBU) and 1,8-bis(dimethylamino)naphthalene (PS) with B(OH)3 in a 1:5 ratio affords in high yields the non-metal cation pentaborate salts [HDBN][B5O6(OH)4] (1), [HDBU][B5O6(OH)4] (2) and [HPS][B5O6(OH)4]·B(OH)3 (3). Compounds 1–3 were characterized by spectroscopic studies (NMR, IR) and compounds 1 and 3 were further characterized by single-crystal XRD studies. The pentaborate salts compounds show extensively H-bonded supramolecular anionic lattices which are templated by the cations. Thermal analysis (TGA) of 1–3 showed that thermally decomposed in air at 1000° to B2O3 in a two step process involving dehydration (

U2 - 10.1016/j.poly.2012.02.031

DO - 10.1016/j.poly.2012.02.031

M3 - Article

SN - 0277-5387

VL - 38

SP - 157

EP - 161

JO - Polyhedron

JF - Polyhedron

IS - 1

ER -