Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes

Maxwell T. P. Rigby; Varun Natu; Maxim Sokol; Daniel J. Kelly; David G. Hopkinson; Yichao Zou; James R. T. Bird; Lee J. Evitts; Matt Smith; Christopher P. Race; Philipp Frankel; Sarah J. Haigh; Michel W. Barsoum

doi:10.1039/D0RA09761F

Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes

Maxwell T. P. Rigby
, Varun Natu
, Maxim Sokol
, Daniel J. Kelly
, David G. Hopkinson
, Yichao Zou
, James R. T. Bird
, Lee J. Evitts
, Matt Smith
, Christopher P. Race
, Philipp Frankel
, Sarah J. Haigh
, Michel W. Barsoum

Ysgol Cyfrifiadureg a Pheirianneg

University of Manchester
Drexel University
University of Tel Aviv, Istael

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

84 Wedi eu Llwytho i Lawr (Pure)

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Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.

Iaith wreiddiol	Saesneg
Cyfnodolyn	RSC Advances
Cyfrol	11
Rhif cyhoeddi	5
Dyddiad ar-lein cynnar	13 Ion 2021
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1039/D0RA09761F
Statws	Cyhoeddwyd - 22 Ion 2021

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10.1039/D0RA09761FTrwydded: CC BY

d0ra09761fFersiwn derfynol wedi’i chyhoeddi, 787 KBTrwydded: CC BY

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Rigby, M. T. P., Natu, V., Sokol, M., Kelly, D. J., Hopkinson, D. G., Zou, Y., Bird, J. R. T., Evitts, L. J., Smith, M., Race, C. P., Frankel, P., Haigh, S. J., & Barsoum, M. W. (2021). Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes. RSC Advances, 11(5). https://doi.org/10.1039/D0RA09761F

@article{b4845836c7bd45ee9fe0d3c3e141b025,

title = "Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes",

abstract = "Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.",

author = "Rigby, \{Maxwell T. P.\} and Varun Natu and Maxim Sokol and Kelly, \{Daniel J.\} and Hopkinson, \{David G.\} and Yichao Zou and Bird, \{James R. T.\} and Evitts, \{Lee J.\} and Matt Smith and Race, \{Christopher P.\} and Philipp Frankel and Haigh, \{Sarah J.\} and Barsoum, \{Michel W.\}",

year = "2021",

month = jan,

day = "22",

doi = "10.1039/D0RA09761F",

language = "English",

volume = "11",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes

AU - Rigby, Maxwell T. P.

AU - Natu, Varun

AU - Sokol, Maxim

AU - Kelly, Daniel J.

AU - Hopkinson, David G.

AU - Zou, Yichao

AU - Bird, James R. T.

AU - Evitts, Lee J.

AU - Smith, Matt

AU - Race, Christopher P.

AU - Frankel, Philipp

AU - Haigh, Sarah J.

AU - Barsoum, Michel W.

PY - 2021/1/22

Y1 - 2021/1/22

N2 - Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.

AB - Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.

U2 - 10.1039/D0RA09761F

DO - 10.1039/D0RA09761F

M3 - Article

SN - 2046-2069

VL - 11

JO - RSC Advances

JF - RSC Advances

IS - 5

ER -

Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes

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