The cycloaddition of cyclopropenes to enones

JR Al Dulayymi; MS Baird; HH Hussain; BJ Alhourani; AMY Alhabashna; SJ Coles; MB Hursthouse

doi:10.1016/S0040-4039(00)00566-9

The cycloaddition of cyclopropenes to enones

JR Al Dulayymi
, MS Baird
, HH Hussain
, BJ Alhourani
, AMY Alhabashna
, SJ Coles
, MB Hursthouse

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

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A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	4205-4208
Nifer y tudalennau	4
Cyfnodolyn	Tetrahedron Letters
Cyfrol	41
Rhif cyhoeddi	21
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1016/S0040-4039(00)00566-9
Statws	Cyhoeddwyd - 29 Mai 2000

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10.1016/S0040-4039(00)00566-9

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@article{3d2ca32b614942ca9d7d0ffa9829b695,

title = "The cycloaddition of cyclopropenes to enones",

abstract = "A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.",

author = "\{Al Dulayymi\}, JR and MS Baird and HH Hussain and BJ Alhourani and AMY Alhabashna and SJ Coles and MB Hursthouse",

year = "2000",

month = may,

day = "29",

doi = "10.1016/S0040-4039(00)00566-9",

language = "English",

volume = "41",

pages = "4205--4208",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "21",

}

TY - JOUR

T1 - The cycloaddition of cyclopropenes to enones

AU - Al Dulayymi, JR

AU - Baird, MS

AU - Hussain, HH

AU - Alhourani, BJ

AU - Alhabashna, AMY

AU - Coles, SJ

AU - Hursthouse, MB

PY - 2000/5/29

Y1 - 2000/5/29

N2 - A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.

AB - A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.

U2 - 10.1016/S0040-4039(00)00566-9

DO - 10.1016/S0040-4039(00)00566-9

M3 - Article

SN - 0040-4039

VL - 41

SP - 4205

EP - 4208

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 21

ER -

The cycloaddition of cyclopropenes to enones

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