Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion

Mohammed Altahan; Michael Beckett; Simon Coles; Peter N. Horton

doi:10.1515/pac-2017-0901

Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion

Mohammed Altahan
, Michael Beckett
, Simon Coles
, Peter N. Horton

University of Southampton

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

296 Wedi eu Llwytho i Lawr (Pure)

Crynodeb

The title compound, [(H3NCH2CH2NH2)Zn{3O,O′,O′′-B12O18(OH)6-1O′′′}Zn(en)(NH2CH2CH2NH3)].8H2O (en = 1,2-diaminoethane) (1), was prepared as a crystalline solid in moderate yield from the reaction of B(OH)3 with [Zn(en)3][OH]2 in aqueous solution (15:1) ratio. The structure contains a neutral bimetallic complex comprised of a unusual dodecaborate(6-) anion ligating two [H3NCH2CH2NH2Zn(en)n]3+ centres in a monodentate (n =1) or tridentate (n = 0) manner.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	625-632
Cyfnodolyn	Pure and Applied Chemistry
Cyfrol	90
Rhif cyhoeddi	4
Dyddiad ar-lein cynnar	17 Hyd 2017
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1515/pac-2017-0901
Statws	Cyhoeddwyd - Ebr 2018

Mynediad at Ddogfen

10.1515/pac-2017-0901

manuscript_BECKETT_revised_CLEANLlawysgrif awdur wedi’i dderbyn, 909 KB

Ôl bys

Gweld gwybodaeth am bynciau ymchwil 'Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion'. Gyda’i gilydd, maen nhw’n ffurfio ôl bys unigryw.

Dyfynnu hyn

Altahan, M., Beckett, M., Coles, S., & Horton, P. N. (2018). Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion. Pure and Applied Chemistry, 90(4), 625-632. https://doi.org/10.1515/pac-2017-0901

Altahan, Mohammed ; Beckett, Michael ; Coles, Simon et al. / Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion. Yn: Pure and Applied Chemistry. 2018 ; Cyfrol 90, Rhif 4. tt. 625-632.

@article{45e2a31a476c4e0ebaf02d4a09525fa2,

title = "Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn\{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′\}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the {\textquoteleft}isolated{\textquoteright} dodecaborate(6−) anion",

abstract = "The title compound, [(H3NCH2CH2NH2)Zn\{3O,O′,O′′-B12O18(OH)6-1O′′′\}Zn(en)(NH2CH2CH2NH3)].8H2O (en = 1,2-diaminoethane) (1), was prepared as a crystalline solid in moderate yield from the reaction of B(OH)3 with [Zn(en)3][OH]2 in aqueous solution (15:1) ratio. The structure contains a neutral bimetallic complex comprised of a unusual dodecaborate(6-) anion ligating two [H3NCH2CH2NH2Zn(en)n]3+ centres in a monodentate (n =1) or tridentate (n = 0) manner.",

author = "Mohammed Altahan and Michael Beckett and Simon Coles and Horton, \{Peter N.\}",

year = "2018",

month = apr,

doi = "10.1515/pac-2017-0901",

language = "English",

volume = "90",

pages = "625--632",

journal = "Pure and Applied Chemistry",

issn = "1365-3075",

publisher = "Walter de Gruyter GmbH",

number = "4",

}

Altahan, M, Beckett, M, Coles, S & Horton, PN 2018, 'Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion', Pure and Applied Chemistry, cyfrol. 90, rhif 4, tt. 625-632. https://doi.org/10.1515/pac-2017-0901

Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion. / Altahan, Mohammed; Beckett, Michael; Coles, Simon et al.
Yn: Pure and Applied Chemistry, Cyfrol 90, Rhif 4, 04.2018, t. 625-632.

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

TY - JOUR

T1 - Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion

AU - Altahan, Mohammed

AU - Beckett, Michael

AU - Coles, Simon

AU - Horton, Peter N.

PY - 2018/4

Y1 - 2018/4

N2 - The title compound, [(H3NCH2CH2NH2)Zn{3O,O′,O′′-B12O18(OH)6-1O′′′}Zn(en)(NH2CH2CH2NH3)].8H2O (en = 1,2-diaminoethane) (1), was prepared as a crystalline solid in moderate yield from the reaction of B(OH)3 with [Zn(en)3][OH]2 in aqueous solution (15:1) ratio. The structure contains a neutral bimetallic complex comprised of a unusual dodecaborate(6-) anion ligating two [H3NCH2CH2NH2Zn(en)n]3+ centres in a monodentate (n =1) or tridentate (n = 0) manner.

AB - The title compound, [(H3NCH2CH2NH2)Zn{3O,O′,O′′-B12O18(OH)6-1O′′′}Zn(en)(NH2CH2CH2NH3)].8H2O (en = 1,2-diaminoethane) (1), was prepared as a crystalline solid in moderate yield from the reaction of B(OH)3 with [Zn(en)3][OH]2 in aqueous solution (15:1) ratio. The structure contains a neutral bimetallic complex comprised of a unusual dodecaborate(6-) anion ligating two [H3NCH2CH2NH2Zn(en)n]3+ centres in a monodentate (n =1) or tridentate (n = 0) manner.

U2 - 10.1515/pac-2017-0901

DO - 10.1515/pac-2017-0901

M3 - Article

SN - 1365-3075

VL - 90

SP - 625

EP - 632

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

IS - 4

ER -

Altahan M, Beckett M, Coles S, Horton PN. Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion. Pure and Applied Chemistry. 2018 Ebr;90(4):625-632. Epub 2017 Hyd 17. doi: 10.1515/pac-2017-0901