A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)

M.A. Altahan; M.A. Beckett; S.J. Coles; P.N. Horton

doi:10.1021/ic5027834

A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)

M.A. Altahan, M.A. Beckett, S.J. Coles, P.N. Horton

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.

Original language	English
Pages (from-to)	412-414
Journal	Inorganic Chemistry
Volume	54
Issue number	2
Early online date	22 Dec 2014
DOIs	https://doi.org/10.1021/ic5027834
Publication status	Published - 2015

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title = "A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)\}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)",

abstract = "The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.",

author = "M.A. Altahan and M.A. Beckett and S.J. Coles and P.N. Horton",

year = "2015",

doi = "10.1021/ic5027834",

language = "English",

volume = "54",

pages = "412--414",

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T1 - A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)

AU - Altahan, M.A.

AU - Beckett, M.A.

AU - Coles, S.J.

AU - Horton, P.N.

PY - 2015

Y1 - 2015

N2 - The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.

AB - The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.

U2 - 10.1021/ic5027834

DO - 10.1021/ic5027834

M3 - Article

SN - 0020-1669

VL - 54

SP - 412

EP - 414

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)

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