Characterization of the hydrides in Stryker's reagent: [HCuP(C 6H5)3]6

E.L. Bennett; P.J. Murphy; S. Imberti; S.F. Parker

doi:10.1021/ic402736t

Characterization of the hydrides in Stryker's reagent: [HCuP(C 6H5)3]6

E.L. Bennett, P.J. Murphy, S. Imberti, S.F. Parker

Research output: Contribution to journal › Article › peer-review

Abstract

A structural, spectroscopic, and computational investigation of Stryker’s reagent, [HCu{P(C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared, inelastic neutron scattering spectroscopies and ab initio studies has allowed the location of most of the modes associated with the hydrides and their assignments.

Original language	English
Pages (from-to)	2963-2967
Number of pages	5
Journal	Inorganic Chemistry
Volume	53
Issue number	6
DOIs	https://doi.org/10.1021/ic402736t https://doi.org/10.1021/ic402736t
Publication status	Published - 26 Feb 2014

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title = "Characterization of the hydrides in Stryker's reagent: [HCuP(C 6H5)3]6",

abstract = "A structural, spectroscopic, and computational investigation of Stryker{\textquoteright}s reagent, [HCu\{P(C6H5)3\}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared, inelastic neutron scattering spectroscopies and ab initio studies has allowed the location of most of the modes associated with the hydrides and their assignments.",

author = "E.L. Bennett and P.J. Murphy and S. Imberti and S.F. Parker",

year = "2014",

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AU - Murphy, P.J.

AU - Imberti, S.

AU - Parker, S.F.

PY - 2014/2/26

Y1 - 2014/2/26

N2 - A structural, spectroscopic, and computational investigation of Stryker’s reagent, [HCu{P(C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared, inelastic neutron scattering spectroscopies and ab initio studies has allowed the location of most of the modes associated with the hydrides and their assignments.

AB - A structural, spectroscopic, and computational investigation of Stryker’s reagent, [HCu{P(C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared, inelastic neutron scattering spectroscopies and ab initio studies has allowed the location of most of the modes associated with the hydrides and their assignments.

U2 - 10.1021/ic402736t

DO - 10.1021/ic402736t

M3 - Article

SN - 0020-1669

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EP - 2967

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Characterization of the hydrides in Stryker's reagent: [HCuP(C 6H5)3]6

Abstract

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