Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis  and N2/H2O/D2O adsorption studies

Lei Liu; Chun-Yang Pan; yong  He; Li-Juan Zhong; Michael Beckett

doi:10.1039/D4DT00117F

Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

Lei Liu, Chun-Yang Pan, yong He, Li-Juan Zhong, Michael Beckett

School of Environmental & Natural Sciences

Guangdong University of Technology

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Abstract

A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.

Original language	English
Pages (from-to)	4637-4642
Number of pages	6
Journal	Dalton Transactions
Volume	53
Issue number	10
Early online date	5 Feb 2024
DOIs	https://doi.org/10.1039/D4DT00117F
Publication status	E-pub ahead of print - 5 Feb 2024

Keywords

Inorganic Chemistry

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10.1039/D4DT00117F

Dalton Transactions 轻重水24.1.30 no yellowAccepted author manuscript, 0.99 MB

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title = "Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies",

abstract = "A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.",

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author = "Lei Liu and Chun-Yang Pan and yong He and Li-Juan Zhong and Michael Beckett",

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T1 - Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

AU - Liu, Lei

AU - Pan, Chun-Yang

AU - He, yong

AU - Zhong, Li-Juan

AU - Beckett, Michael

PY - 2024/2/5

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N2 - A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.

AB - A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.

KW - Inorganic Chemistry

U2 - 10.1039/D4DT00117F

DO - 10.1039/D4DT00117F

M3 - Article

SN - 1477-9226

VL - 53

SP - 4637

EP - 4642

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

Abstract

Keywords

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