Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis  and N2/H2O/D2O adsorption studies

Lei Liu; Chun-Yang Pan; yong  He; Li-Juan Zhong; Michael Beckett

doi:10.1039/D4DT00117F

Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

Lei Liu
, Chun-Yang Pan
, yong He
, Li-Juan Zhong
, Michael Beckett

School of Environmental & Natural Sciences

Guangdong University of Technology

Research output: Contribution to journal › Article › peer-review

33 Downloads (Pure)

Abstract

A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.

Original language	English
Pages (from-to)	4637-4642
Number of pages	6
Journal	Dalton Transactions
Volume	53
Issue number	10
Early online date	5 Feb 2024
DOIs	https://doi.org/10.1039/D4DT00117F
Publication status	E-pub ahead of print - 5 Feb 2024

Keywords

Inorganic Chemistry

Access to Document

10.1039/D4DT00117F

Dalton Transactions 轻重水24.1.30 no yellowAccepted author manuscript, 0.99 MB

Cite this

@article{861779cdd61a4f9a908754861957d549,

title = "Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies",

abstract = "A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.",

keywords = "Inorganic Chemistry",

author = "Lei Liu and Chun-Yang Pan and yong He and Li-Juan Zhong and Michael Beckett",

year = "2024",

month = feb,

day = "5",

doi = "10.1039/D4DT00117F",

language = "English",

volume = "53",

pages = "4637--4642",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

AU - Liu, Lei

AU - Pan, Chun-Yang

AU - He, yong

AU - Zhong, Li-Juan

AU - Beckett, Michael

PY - 2024/2/5

Y1 - 2024/2/5

N2 - A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.

AB - A series of hybrid tetraborates [ZnxCo(1−x)(1,3-dap)B4O7] were synthesized. This study demonstrates that [ZnxCo(1−x)(1,3-dap)B4O7] exhibits a higher adsorption affinity for H2O compared to D2O, leading to an enrichment of D2O content in mixtures of H2O and D2O.

KW - Inorganic Chemistry

U2 - 10.1039/D4DT00117F

DO - 10.1039/D4DT00117F

M3 - Article

SN - 1477-9226

VL - 53

SP - 4637

EP - 4642

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap = 1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

Abstract

Keywords

Access to Document

Fingerprint

Cite this