Iodotris(triphenylphosphine)silver(I), [Ag(PPh3)3I]

DE Hibbs; MB Hursthouse; KMA Malik; MA Beckett

doi:10.1107/S0108270195015228

Iodotris(triphenylphosphine)silver(I), [Ag(PPh3)3I]

DE Hibbs
, MB Hursthouse
, KMA Malik
, MA Beckett

Research output: Contribution to journal › Article › peer-review

Abstract

The geometry about the Ag atom in the title complex, C54H45AgIP3, is distorted tetrahedral with the Ag-I bond length 2.8660 (11) Å and Ag-P distances 2.5335 (14), 2.5589 (12) and 2.6814 (12) Å. The P-Ag-P/I angles show large variations [104.54 (3) to 116.10 (4)°] from the ideal tetrahedral value (109.45°). These distortions, as well as those around the P atoms in the three triphenylphosphine ligands, may be attributed to several intramolecular (H...I and H...C/H) short contacts.

Original language	English
Pages (from-to)	884-887
Number of pages	4
Journal	Acta Crystallographica Section C Crystal Structure Communications
Volume	52
DOIs	https://doi.org/10.1107/S0108270195015228
Publication status	Published - 1996

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@article{c8bd2ff9f3a94316b63c34bb54ce7a1b,

title = "Iodotris(triphenylphosphine)silver(I), [Ag(PPh3)3I]",

abstract = "The geometry about the Ag atom in the title complex, C54H45AgIP3, is distorted tetrahedral with the Ag-I bond length 2.8660 (11) {\AA} and Ag-P distances 2.5335 (14), 2.5589 (12) and 2.6814 (12) {\AA}. The P-Ag-P/I angles show large variations [104.54 (3) to 116.10 (4)°] from the ideal tetrahedral value (109.45°). These distortions, as well as those around the P atoms in the three triphenylphosphine ligands, may be attributed to several intramolecular (H...I and H...C/H) short contacts.",

author = "DE Hibbs and MB Hursthouse and KMA Malik and MA Beckett",

year = "1996",

doi = "10.1107/S0108270195015228",

language = "English",

volume = "52",

pages = "884--887",

journal = "Acta Crystallographica Section C Crystal Structure Communications",

issn = "2053-2296",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Iodotris(triphenylphosphine)silver(I), [Ag(PPh3)3I]

AU - Hibbs, DE

AU - Hursthouse, MB

AU - Malik, KMA

AU - Beckett, MA

PY - 1996

Y1 - 1996

N2 - The geometry about the Ag atom in the title complex, C54H45AgIP3, is distorted tetrahedral with the Ag-I bond length 2.8660 (11) Å and Ag-P distances 2.5335 (14), 2.5589 (12) and 2.6814 (12) Å. The P-Ag-P/I angles show large variations [104.54 (3) to 116.10 (4)°] from the ideal tetrahedral value (109.45°). These distortions, as well as those around the P atoms in the three triphenylphosphine ligands, may be attributed to several intramolecular (H...I and H...C/H) short contacts.

AB - The geometry about the Ag atom in the title complex, C54H45AgIP3, is distorted tetrahedral with the Ag-I bond length 2.8660 (11) Å and Ag-P distances 2.5335 (14), 2.5589 (12) and 2.6814 (12) Å. The P-Ag-P/I angles show large variations [104.54 (3) to 116.10 (4)°] from the ideal tetrahedral value (109.45°). These distortions, as well as those around the P atoms in the three triphenylphosphine ligands, may be attributed to several intramolecular (H...I and H...C/H) short contacts.

U2 - 10.1107/S0108270195015228

DO - 10.1107/S0108270195015228

M3 - Article

SN - 2053-2296

VL - 52

SP - 884

EP - 887

JO - Acta Crystallographica Section C Crystal Structure Communications

JF - Acta Crystallographica Section C Crystal Structure Communications

ER -

Iodotris(triphenylphosphine)silver(I), [Ag(PPh3)3I]

Abstract

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