Mycolyl arabino glycerols from synthetic mycolic acids

M.O. Mohammed; M.S. Baird; Juma'a Al-Dulayymi

doi:10.1016/j.tetlet.2015.01.070

Mycolyl arabino glycerols from synthetic mycolic acids

M.O. Mohammed, M.S. Baird, Juma'a Al-Dulayymi

Research output: Contribution to journal › Article › peer-review

Abstract

Synthesis of single enantiomers of mycolyl arabino glycerols, glycolipids previously isolated from Mycobacterium avium–Mycobacterium intracellulare complex, is described using a modified glycosidation method and esterification with structurally defined synthetic mycolic acids. The l-glycero-compound has an essentially identical NMR spectrum to the arabino-glycerol fragment of the natural material.

Original language	English
Pages (from-to)	3268–3272
Journal	Tetrahedron Letters
Volume	56
Issue number	23
DOIs	https://doi.org/10.1016/j.tetlet.2015.01.070
Publication status	Published - 16 Jan 2015

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10.1016/j.tetlet.2015.01.070

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title = "Mycolyl arabino glycerols from synthetic mycolic acids",

abstract = "Synthesis of single enantiomers of mycolyl arabino glycerols, glycolipids previously isolated from Mycobacterium avium–Mycobacterium intracellulare complex, is described using a modified glycosidation method and esterification with structurally defined synthetic mycolic acids. The l-glycero-compound has an essentially identical NMR spectrum to the arabino-glycerol fragment of the natural material.",

author = "M.O. Mohammed and M.S. Baird and Juma'a Al-Dulayymi",

year = "2015",

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day = "16",

doi = "10.1016/j.tetlet.2015.01.070",

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AU - Mohammed, M.O.

AU - Baird, M.S.

AU - Al-Dulayymi, Juma'a

PY - 2015/1/16

Y1 - 2015/1/16

N2 - Synthesis of single enantiomers of mycolyl arabino glycerols, glycolipids previously isolated from Mycobacterium avium–Mycobacterium intracellulare complex, is described using a modified glycosidation method and esterification with structurally defined synthetic mycolic acids. The l-glycero-compound has an essentially identical NMR spectrum to the arabino-glycerol fragment of the natural material.

AB - Synthesis of single enantiomers of mycolyl arabino glycerols, glycolipids previously isolated from Mycobacterium avium–Mycobacterium intracellulare complex, is described using a modified glycosidation method and esterification with structurally defined synthetic mycolic acids. The l-glycero-compound has an essentially identical NMR spectrum to the arabino-glycerol fragment of the natural material.

U2 - 10.1016/j.tetlet.2015.01.070

DO - 10.1016/j.tetlet.2015.01.070

M3 - Article

SN - 0040-4039

VL - 56

SP - 3268

EP - 3272

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 23

ER -

Mycolyl arabino glycerols from synthetic mycolic acids

Abstract

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