Recent advances in crystalline hydrated borates with non-metal or transition-metal complex cations

Michael Beckett

doi:10.1016/j.ccr.2015.12.012

Recent advances in crystalline hydrated borates with non-metal or transition-metal complex cations

Michael Beckett

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Abstract

Structural aspects of crystalline hydrated polyborate salts containing polyborate anions partnered with either cationic transition-metal complexes or non-metal (organic) cations are documented. The structures are described in terms of Christ and Clark's and Burns’ descriptors. The review, which concentrates on the period 2000–2015, also describes synthetic approaches (hydrothermal, solvothermal, flux methods) and physical and spectroscopic properties of the polyborate salts.

Original language	English
Pages (from-to)	2-14
Journal	Coordination Chemistry Reviews
Volume	323
Early online date	8 Jan 2016
DOIs	https://doi.org/10.1016/j.ccr.2015.12.012
Publication status	Published - 15 Sept 2016

Keywords

Hydrated borates
Non-metal cations
Polyborate anions
ransition-metal complex cations
XRD

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10.1016/j.ccr.2015.12.012Licence: CC BY-NC-ND

Coord Chem Rev 2016Accepted author manuscript, 879 KBLicence: CC BY-NC-ND

Cite this

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abstract = "Structural aspects of crystalline hydrated polyborate salts containing polyborate anions partnered with either cationic transition-metal complexes or non-metal (organic) cations are documented. The structures are described in terms of Christ and Clark's and Burns{\textquoteright} descriptors. The review, which concentrates on the period 2000–2015, also describes synthetic approaches (hydrothermal, solvothermal, flux methods) and physical and spectroscopic properties of the polyborate salts.",

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AB - Structural aspects of crystalline hydrated polyborate salts containing polyborate anions partnered with either cationic transition-metal complexes or non-metal (organic) cations are documented. The structures are described in terms of Christ and Clark's and Burns’ descriptors. The review, which concentrates on the period 2000–2015, also describes synthetic approaches (hydrothermal, solvothermal, flux methods) and physical and spectroscopic properties of the polyborate salts.

KW - Hydrated borates

KW - Non-metal cations

KW - Polyborate anions

KW - ransition-metal complex cations

KW - XRD

U2 - 10.1016/j.ccr.2015.12.012

DO - 10.1016/j.ccr.2015.12.012

M3 - Article

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VL - 323

SP - 2

EP - 14

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

ER -

Recent advances in crystalline hydrated borates with non-metal or transition-metal complex cations

Abstract

Keywords

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