Tandem rearrangements of a cyclic bis-allene

H.H. Mustafa; M.S. Baird; J.R. Al-Dulayymi; V. Tverezovskiy

doi:10.1016/j.tet.2013.12.058

Tandem rearrangements of a cyclic bis-allene

H.H. Mustafa, M.S. Baird, J.R. Al-Dulayymi, V. Tverezovskiy

BioComposites

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Abstract

Reaction of the bis-dibromocarbene adduct of cyclonona-1,4,7-triene with methyllithium leads to a mixture of meso and racemic cycloundeca-1,2,5,6,9-pentaenes; the former rearranges at ambient temperature through a set of pericyclic reactions

Original language	English
Pages (from-to)	1502-1507
Journal	Tetrahedron
Volume	70
Issue number	7
Early online date	8 Jan 2014
DOIs	https://doi.org/10.1016/j.tet.2013.12.058
Publication status	Published - 18 Feb 2014

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title = "Tandem rearrangements of a cyclic bis-allene",

abstract = "Reaction of the bis-dibromocarbene adduct of cyclonona-1,4,7-triene with methyllithium leads to a mixture of meso and racemic cycloundeca-1,2,5,6,9-pentaenes; the former rearranges at ambient temperature through a set of pericyclic reactions",

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AU - Mustafa, H.H.

AU - Baird, M.S.

AU - Al-Dulayymi, J.R.

AU - Tverezovskiy, V.

PY - 2014/2/18

Y1 - 2014/2/18

N2 - Reaction of the bis-dibromocarbene adduct of cyclonona-1,4,7-triene with methyllithium leads to a mixture of meso and racemic cycloundeca-1,2,5,6,9-pentaenes; the former rearranges at ambient temperature through a set of pericyclic reactions

AB - Reaction of the bis-dibromocarbene adduct of cyclonona-1,4,7-triene with methyllithium leads to a mixture of meso and racemic cycloundeca-1,2,5,6,9-pentaenes; the former rearranges at ambient temperature through a set of pericyclic reactions

U2 - 10.1016/j.tet.2013.12.058

DO - 10.1016/j.tet.2013.12.058

M3 - Article

SN - 0040-4020

VL - 70

SP - 1502

EP - 1507

JO - Tetrahedron

JF - Tetrahedron

IS - 7

ER -

Tandem rearrangements of a cyclic bis-allene

Abstract

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