The cycloaddition of cyclopropenes to enones

JR Al Dulayymi; MS Baird; HH Hussain; BJ Alhourani; AMY Alhabashna; SJ Coles; MB Hursthouse

doi:10.1016/S0040-4039(00)00566-9

The cycloaddition of cyclopropenes to enones

JR Al Dulayymi, MS Baird, HH Hussain, BJ Alhourani, AMY Alhabashna, SJ Coles, MB Hursthouse

Research output: Contribution to journal › Article › peer-review

Abstract

A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	4205-4208
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	21
DOIs	https://doi.org/10.1016/S0040-4039(00)00566-9
Publication status	Published - 29 May 2000

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title = "The cycloaddition of cyclopropenes to enones",

abstract = "A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.",

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doi = "10.1016/S0040-4039(00)00566-9",

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T1 - The cycloaddition of cyclopropenes to enones

AU - Al Dulayymi, JR

AU - Baird, MS

AU - Hussain, HH

AU - Alhourani, BJ

AU - Alhabashna, AMY

AU - Coles, SJ

AU - Hursthouse, MB

PY - 2000/5/29

Y1 - 2000/5/29

N2 - A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.

AB - A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.

U2 - 10.1016/S0040-4039(00)00566-9

DO - 10.1016/S0040-4039(00)00566-9

M3 - Article

SN - 0040-4039

VL - 41

SP - 4205

EP - 4208

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 21

ER -

The cycloaddition of cyclopropenes to enones

Abstract

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