Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties

M.A. Beckett; P.N. Horton; M.B. Hursthouse; J.L. Timmis

doi:10.1039/C3RA42387E

Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties

M.A. Beckett, P.N. Horton, M.B. Hursthouse, J.L. Timmis

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Abstract

The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (

Original language	English
Pages (from-to)	15185-15191
Journal	RSC Advances
Volume	3
DOIs	https://doi.org/10.1039/C3RA42387E
Publication status	Published - 17 Jun 2013

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title = "Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties",

abstract = "The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (",

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T1 - Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties

AU - Beckett, M.A.

AU - Horton, P.N.

AU - Hursthouse, M.B.

AU - Timmis, J.L.

PY - 2013/6/17

Y1 - 2013/6/17

N2 - The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (

AB - The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (

U2 - 10.1039/C3RA42387E

DO - 10.1039/C3RA42387E

M3 - Article

SN - 2046-2069

VL - 3

SP - 15185

EP - 15191

JO - RSC Advances

JF - RSC Advances

ER -

Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties

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