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A Facile Synthetic Route to a Family of Mn(III) Monomers and their Structural, Magnetic and Spectroscopic Studies. / Jones, Leigh; Barra, Anne-Laure; Ryder, Alan G.; Brechin, Euan K.; Collison, David; Innes, Eric J.L.; Sanz, Sergio; Kelly, Brian; Houton, Edel.

Yn: European Journal of Inorganic Chemistry , Cyfrol 2016, Rhif 32, 11.2016, t. 5123-5131.

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygl

HarvardHarvard

Jones, L, Barra, A-L, Ryder, AG, Brechin, EK, Collison, D, Innes, EJL, Sanz, S, Kelly, B & Houton, E 2016, 'A Facile Synthetic Route to a Family of Mn(III) Monomers and their Structural, Magnetic and Spectroscopic Studies', European Journal of Inorganic Chemistry , cyfrol. 2016, rhif 32, tt. 5123-5131. https://doi.org/10.1002/ejic.201601124

APA

Jones, L., Barra, A-L., Ryder, A. G., Brechin, E. K., Collison, D., Innes, E. J. L., ... Houton, E. (2016). A Facile Synthetic Route to a Family of Mn(III) Monomers and their Structural, Magnetic and Spectroscopic Studies. European Journal of Inorganic Chemistry , 2016(32), 5123-5131. https://doi.org/10.1002/ejic.201601124

CBE

Jones L, Barra A-L, Ryder AG, Brechin EK, Collison D, Innes EJL, Sanz S, Kelly B, Houton E. 2016. A Facile Synthetic Route to a Family of Mn(III) Monomers and their Structural, Magnetic and Spectroscopic Studies. European Journal of Inorganic Chemistry . 2016(32):5123-5131. https://doi.org/10.1002/ejic.201601124

MLA

VancouverVancouver

Jones L, Barra A-L, Ryder AG, Brechin EK, Collison D, Innes EJL et al. A Facile Synthetic Route to a Family of Mn(III) Monomers and their Structural, Magnetic and Spectroscopic Studies. European Journal of Inorganic Chemistry . 2016 Nov;2016(32):5123-5131. https://doi.org/10.1002/ejic.201601124

Author

Jones, Leigh ; Barra, Anne-Laure ; Ryder, Alan G. ; Brechin, Euan K. ; Collison, David ; Innes, Eric J.L. ; Sanz, Sergio ; Kelly, Brian ; Houton, Edel. / A Facile Synthetic Route to a Family of Mn(III) Monomers and their Structural, Magnetic and Spectroscopic Studies. Yn: European Journal of Inorganic Chemistry . 2016 ; Cyfrol 2016, Rhif 32. tt. 5123-5131.

RIS

TY - JOUR

T1 - A Facile Synthetic Route to a Family of Mn(III) Monomers and their Structural, Magnetic and Spectroscopic Studies

AU - Jones, Leigh

AU - Barra, Anne-Laure

AU - Ryder, Alan G.

AU - Brechin, Euan K.

AU - Collison, David

AU - Innes, Eric J.L.

AU - Sanz, Sergio

AU - Kelly, Brian

AU - Houton, Edel

N1 - Funded by Engineering and Physical Sciences Research Council; Irish Research Council for Science, Engineering and Technology

PY - 2016/11

Y1 - 2016/11

N2 - We report a rapid and facile route to the synthesis of a family of MnIII monomers of general formula [MnIIIF3(H2O)(L1–6)]·xH2O·yMeOH [L1 = 2,2′-bipyridyl, x = 2, y = 0 (1′); L2 = 1,10′-phenanthroline, x = y = 0 (2′); L3 = 6-methyl-2,2′-dipyridyl, x = y = 0 (3), L4 = 4,4-dimethyl-2,2′-dipyridyl, x = 2, y = 0 (4), L5 = 5,5′-dimethyl-2,2′-dipyridyl, x = 0, y = 0.5 (5); L6 = 5-chloro-1,10-phenanthroline, x = y = 0 (6)]. Magnetic susceptibility and magnetisation experiments have been employed to elucidate the D tensor for each family member (ranging from –3.01 cm–1 in 2′ to –4.02 cm–1 in 5), while multi-frequency/high-field EPR spectroscopic measurements and subsequent simulations gave similar values for complexes 1′ (–4.25 cm–1), 2′ (–4.03 cm–1), 4 (–3.90 cm–1) and 5 (–4.04 cm–1). The terminal Mn–F vibrational stretches in 1′–6 have been probed using Raman spectroscopy.

AB - We report a rapid and facile route to the synthesis of a family of MnIII monomers of general formula [MnIIIF3(H2O)(L1–6)]·xH2O·yMeOH [L1 = 2,2′-bipyridyl, x = 2, y = 0 (1′); L2 = 1,10′-phenanthroline, x = y = 0 (2′); L3 = 6-methyl-2,2′-dipyridyl, x = y = 0 (3), L4 = 4,4-dimethyl-2,2′-dipyridyl, x = 2, y = 0 (4), L5 = 5,5′-dimethyl-2,2′-dipyridyl, x = 0, y = 0.5 (5); L6 = 5-chloro-1,10-phenanthroline, x = y = 0 (6)]. Magnetic susceptibility and magnetisation experiments have been employed to elucidate the D tensor for each family member (ranging from –3.01 cm–1 in 2′ to –4.02 cm–1 in 5), while multi-frequency/high-field EPR spectroscopic measurements and subsequent simulations gave similar values for complexes 1′ (–4.25 cm–1), 2′ (–4.03 cm–1), 4 (–3.90 cm–1) and 5 (–4.04 cm–1). The terminal Mn–F vibrational stretches in 1′–6 have been probed using Raman spectroscopy.

U2 - 10.1002/ejic.201601124

DO - 10.1002/ejic.201601124

M3 - Article

VL - 2016

SP - 5123

EP - 5131

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 32

ER -