Characterization of the hydrides in Stryker's reagent: [HCuP(C 6H5)3]6
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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Yn: Inorganic Chemistry, Cyfrol 53, Rhif 6, 26.02.2014, t. 2963-2967.
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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TY - JOUR
T1 - Characterization of the hydrides in Stryker's reagent
T2 - [HCuP(C 6H5)3]6
AU - Bennett, E.L.
AU - Murphy, P.J.
AU - Imberti, S.
AU - Parker, S.F.
PY - 2014/2/26
Y1 - 2014/2/26
N2 - A structural, spectroscopic, and computational investigation of Stryker’s reagent, [HCu{P(C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared, inelastic neutron scattering spectroscopies and ab initio studies has allowed the location of most of the modes associated with the hydrides and their assignments.
AB - A structural, spectroscopic, and computational investigation of Stryker’s reagent, [HCu{P(C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared, inelastic neutron scattering spectroscopies and ab initio studies has allowed the location of most of the modes associated with the hydrides and their assignments.
U2 - 10.1021/ic402736t
DO - 10.1021/ic402736t
M3 - Article
VL - 53
SP - 2963
EP - 2967
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 6
ER -