Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3.
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- 2019-Copper(2+) complexes
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Dangosydd eitem ddigidol (DOI)
The pentaborate(1-) salt, [Cu(dmen)2(H2O)2][B5O6(OH)4]2.2B(OH)3(dmen = N,N’-dimethylethylenediamine, MeHNCH2CH2NHMe), has been synthesized in 48% yield as a crystalline product by reaction of B(OH)3 with [Cu(dmen)2](OH)2]2 (10:1 ratio) in aqueous solution. Single-crystal XRD analysis confirms its ionic structure with one interstitial B(OH)3 per pentaborate(1-) unit. The pentaborate(1-) anions and B(OH)3 molecules are involved in a supramolecular giant H-bonded lattice with B(OH)3 units serving as ‘spacers’ to help accommodate the relatively large [Cu(dmen)2(H2O)2]2+ cations
Allweddeiriau
| Iaith wreiddiol | Saesneg |
|---|---|
| Tudalennau (o-i) | 948-951 |
| Cyfnodolyn | Phosphorus, Sulfur and Silicon and the Related Elements |
| Cyfrol | 194 |
| Rhif y cyfnodolyn | 10 |
| Dyddiad ar-lein cynnar | 20 Meh 2019 |
| Dynodwyr Gwrthrych Digidol (DOIs) | |
| Statws | Cyhoeddwyd - 3 Hyd 2019 |
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