Maximum-entropy closure of hydrodynamic moment hierarchies including correlations

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

Fersiynau electronig

Dangosydd eitem ddigidol (DOI)

Generalized hydrodynamic moment hierarchies are derived which explicitly include nonequilibrium two-particle and higher-order correlations. The approach is adapted to strongly correlated media and nonequilibrium processes on short time scales which necessitate an explicit treatment of time-evolving correlations. Closure conditions for the extended moment hierarchies are formulated by a maximum-entropy approach, generalizing related closure procedures for kinetic equations. A self-consistent set of nonperturbative dynamical equations are thus obtained for a chosen set of single-particle and two-particle (and possibly higher-order) moments. Analytical results are derived for generalized Gaussian closures including the dynamic pair distribution function and a two-particle correction to the current density. The maximum-entropy closure conditions are found to involve the Kirkwood superposition approximation.
Iaith wreiddiolSaesneg
Rhif yr erthyglArticle 214109
CyfnodolynJournal of Chemical Physics
Cyfrol136
Rhif y cyfnodolyn21
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 7 Meh 2012
Gweld graff cysylltiadau