Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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Yn: Tetrahedron Letters, Cyfrol 54, Rhif 10, 06.03.2013, t. 1227-1229.
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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T1 - Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system
AU - Charlton, A.
AU - Donati, D.
AU - Fusi, S.
AU - Murphy, P.J.
AU - Ponticelli, F.
N1 - The work was financially supported by the PRIN Project 2009
PY - 2013/3/6
Y1 - 2013/3/6
N2 - Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.
AB - Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.
U2 - 10.1016/j.tetlet.2012.12.080
DO - 10.1016/j.tetlet.2012.12.080
M3 - Article
VL - 54
SP - 1227
EP - 1229
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 10
ER -