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Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system. / Charlton, A.; Donati, D.; Fusi, S. et al.
Yn: Tetrahedron Letters, Cyfrol 54, Rhif 10, 06.03.2013, t. 1227-1229.

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TY - JOUR

T1 - Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system

AU - Charlton, A.

AU - Donati, D.

AU - Fusi, S.

AU - Murphy, P.J.

AU - Ponticelli, F.

N1 - The work was financially supported by the PRIN Project 2009

PY - 2013/3/6

Y1 - 2013/3/6

N2 - Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.

AB - Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.

U2 - 10.1016/j.tetlet.2012.12.080

DO - 10.1016/j.tetlet.2012.12.080

M3 - Article

VL - 54

SP - 1227

EP - 1229

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 10

ER -