Synthesis and characterization of templated pentaborate(1-) salts: X-ray structure of [(2-HOCH2CH2)C4H7NMeH][B5O6(OH)4]·0.3H2O
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Fersiynau electronig
Dogfennau
- PS Si 2016 vol 191 p628
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Dangosydd eitem ddigidol (DOI)
The synthesis of pyrrolidinium pentaborate(1-) and four substituted pyrrolidinium pentaborate(1-) salts from B(OH)3 in aqueous solution are reported. Characterization (Infrared, nuclear magnetic resonance, and single-crystal X-ray power diffraction) of [(2-HOCH2CH2)C4H7NH2] [B5O6(OH)4]0.3H2O is described in detail. The cation is the largest of the five pyrrolidinium cations studied. A consequence of this is that its solid-state structure has anion–anion interactions (αααγ), which are different from the other four (αααβ) structures. There are also stabilizing cation–anion H-bond interactions.
Allweddeiriau
| Iaith wreiddiol | Saesneg |
|---|---|
| Tudalennau (o-i) | 628-630 |
| Cyfnodolyn | Phosphorus, Sulfur and Silicon and the Related Elements |
| Cyfrol | 191 |
| Rhif y cyfnodolyn | 4 |
| Dyddiad ar-lein cynnar | 6 Chwef 2016 |
| Dynodwyr Gwrthrych Digidol (DOIs) | |
| Statws | Cyhoeddwyd - 1 Awst 2016 |
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