Synthesis and XRD study of an C2-linked bis(quaternary ammonium) pentaborate: [Me3NCH2CH2NMe3][B5O6(OH)4]2
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- 2019-Synthesis and XRD study
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Dangosydd eitem ddigidol (DOI)
The synthesis and characterization of a C2 (ethane) linked bis(trimethylammonium) pentaborate salt, [Me3NCH2CH2NMe3][B5O6(OH)4]2 (1), is reported . Compound 1 has been characterized by 1H, 11B, and 13C NMR Spectroscopy, IR spectroscopy, thermal (TGA/DSC) analysis, and single-crystal X-ray diffraction. There are two independent crystallographic pentaborate(1-) anions in the solid-state structure and these link by H-bonds at -sites into a centrosymmetric tetrameric chain. These chains are crossed-linked by R22(8) H-bond motifs to -sites of neighbouring pentaborate tetrameric units. The [Me3NCH2CH2NMe3]2+ cations are located between these tetrameric pentaborate(1-) units.
Allweddeiriau
| Iaith wreiddiol | Saesneg |
|---|---|
| Tudalennau (o-i) | 952-955 |
| Cyfnodolyn | Phosphorus, Sulfur and Silicon and the Related Elements |
| Cyfrol | 194 |
| Rhif y cyfnodolyn | 10 |
| Dyddiad ar-lein cynnar | 20 Meh 2019 |
| Dynodwyr Gwrthrych Digidol (DOIs) | |
| Statws | Cyhoeddwyd - 3 Hyd 2019 |
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