Porth Ymchwil

Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane)

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

StandardStandard

Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane). / Altahan, Mohammed; Beckett, Michael; Coles, Simon J. et al.
Yn: Crystals, Cyfrol 8, Rhif 12, 470, 14.12.2018.

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

HarvardHarvard

Altahan, M, Beckett, M, Coles, SJ & Horton, PN 2018, 'Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane)', Crystals, cyfrol. 8, rhif 12, 470.

APA

Altahan, M., Beckett, M., Coles, S. J., & Horton, P. N. (2018). Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane). Crystals, 8(12), Erthygl 470.

CBE

Altahan M, Beckett M, Coles SJ, Horton PN. 2018. Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane). Crystals. 8(12):Article 470.

MLA

Altahan, Mohammed et al. "Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane)". Crystals. 2018. 8(12).

VancouverVancouver

Altahan M, Beckett M, Coles SJ, Horton PN. Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane). Crystals. 2018 Rhag 14;8(12):470.

Author

Altahan, Mohammed ; Beckett, Michael ; Coles, Simon J. et al. / Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane). Yn: Crystals. 2018 ; Cyfrol 8, Rhif 12.

RIS

TY - JOUR

T1 - Two 1-D Coordination Polymers containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane)

AU - Altahan, Mohammed

AU - Beckett, Michael

AU - Coles, Simon J.

AU - Horton, Peter N.

N1 - Invited manuscript as (waived APC) as featured article in a special issue on 'self-assembled supramolecular polymers via strong H bonding".

PY - 2018/12/14

Y1 - 2018/12/14

N2 - The synthesis and characterization by single-crystal XRD studies of two new zinc(II) hexaborate(2-) complexes, [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) (1) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane) (2) are reported. These complexes crystallize from aqueous solutions containing 10:1 ratios of B(OH)3 and the appropriate Zn(II) amine complexes ([Zn(en)3][OH]2 or [Zn(pn)3][OH]2) through self-assembly processes. The hexaborate(2-) anions in 1 and 2 are coordinated to two Zn(II) centres and form 1-D polymeric coordination chains. R22(8) and R22(6) inter-chain H-bond interactions play an important role in these self-assembly processes and are discussed.

AB - The synthesis and characterization by single-crystal XRD studies of two new zinc(II) hexaborate(2-) complexes, [Zn(en){B6O7(OH)6}].2H2O (en = 1,2-diaminoethane) (1) and [Zn(pn){B6O7(OH)6}].1.5H2O (pn = 1,2-diaminopropane) (2) are reported. These complexes crystallize from aqueous solutions containing 10:1 ratios of B(OH)3 and the appropriate Zn(II) amine complexes ([Zn(en)3][OH]2 or [Zn(pn)3][OH]2) through self-assembly processes. The hexaborate(2-) anions in 1 and 2 are coordinated to two Zn(II) centres and form 1-D polymeric coordination chains. R22(8) and R22(6) inter-chain H-bond interactions play an important role in these self-assembly processes and are discussed.

KW - Coordination polymer (1-D); H-bond; Hexaborate(2-); Oxidoborate; Polyborate; Self-assembly; X-ray structure; Zinc(II) complex

M3 - Article

VL - 8

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 12

M1 - 470

ER -