The simple rules that govern the interactions between the different components of a complex system often lead to interesting behaviours that are unexpected. The experiments described in this paper involved creating a variation of a traditional Braitenberg Vehicle, by placing sensors on ten different possible locations on a simulated vehicle, and incorporating an obstacle avoidance behaviour using a subsumption-like architecture, which resulted in different unusual and unexpected behaviours being produced. The vehicle was allowed to explore a simulated environment which contained a single bright light in the centre with walls on the border. By using a novel combination of the Prediction by Partial Matching compression algorithm and k-means clustering, interesting emergent behaviours were effectively discovered within a search space of over 10,000 simulations produced from a simple interaction of light and proximity sensors on a vehicle and a single light source. The clustering algorithm discovered five distinct behaviours: circling and spiralling behaviours; interesting behaviours creating intricate rose petal-like structures; behaviours that create simple rose petal-like structures; behaviours with large movements and low complexity; and behaviours with less movement. The novel algorithm demonstrated in this paper has useful potential in the science of complex systems and modelling to help expedite the systematic exploration of a substantial search space of simulations in order to discover interesting behaviours.