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4,5-Diazafluorene co-oligomers as electrondeficientlight-emitting materials and selectivefluorescence sensors for mercury(II) cations. / Ghosh, Sanjay; Alghunaim, Abulaziz S.; AL-Mashhadani, Mohammed et al.
In: Journal of Materials Chemistry C, Vol. 6, No. 14, 14.04.2018, p. 3762-3773 .

Research output: Contribution to journalArticlepeer-review

HarvardHarvard

Ghosh, S, Alghunaim, AS, AL-Mashhadani, M, Krompiec, MP, Hallett, M & Perepichka, I 2018, '4,5-Diazafluorene co-oligomers as electrondeficientlight-emitting materials and selectivefluorescence sensors for mercury(II) cations', Journal of Materials Chemistry C, vol. 6, no. 14, pp. 3762-3773 . https://doi.org/10.1039/C7TC05051H

APA

Ghosh, S., Alghunaim, A. S., AL-Mashhadani, M., Krompiec, M. P., Hallett, M., & Perepichka, I. (2018). 4,5-Diazafluorene co-oligomers as electrondeficientlight-emitting materials and selectivefluorescence sensors for mercury(II) cations. Journal of Materials Chemistry C, 6(14), 3762-3773 . https://doi.org/10.1039/C7TC05051H

CBE

Ghosh S, Alghunaim AS, AL-Mashhadani M, Krompiec MP, Hallett M, Perepichka I. 2018. 4,5-Diazafluorene co-oligomers as electrondeficientlight-emitting materials and selectivefluorescence sensors for mercury(II) cations. Journal of Materials Chemistry C. 6(14):3762-3773 . https://doi.org/10.1039/C7TC05051H

MLA

VancouverVancouver

Ghosh S, Alghunaim AS, AL-Mashhadani M, Krompiec MP, Hallett M, Perepichka I. 4,5-Diazafluorene co-oligomers as electrondeficientlight-emitting materials and selectivefluorescence sensors for mercury(II) cations. Journal of Materials Chemistry C. 2018 Apr 14;6(14):3762-3773 . Epub 2018 Jan 31. doi: 10.1039/C7TC05051H

Author

Ghosh, Sanjay ; Alghunaim, Abulaziz S. ; AL-Mashhadani, Mohammed et al. / 4,5-Diazafluorene co-oligomers as electrondeficientlight-emitting materials and selectivefluorescence sensors for mercury(II) cations. In: Journal of Materials Chemistry C. 2018 ; Vol. 6, No. 14. pp. 3762-3773 .

RIS

TY - JOUR

T1 - 4,5-Diazafluorene co-oligomers as electrondeficientlight-emitting materials and selectivefluorescence sensors for mercury(II) cations

AU - Ghosh, Sanjay

AU - Alghunaim, Abulaziz S.

AU - AL-Mashhadani, Mohammed

AU - Krompiec, Michal Piotr

AU - Hallett, Megan

AU - Perepichka, Igor

PY - 2018/4/14

Y1 - 2018/4/14

N2 - A series of 4,5-diazafluorene-based (N) conjugated co-oligomers with 9,9-dialkylfluorene (F) or electron-deficient dibenzothiophene-S,S-dioxide (S) has been synthesized by Pd-catalyzed coupling reaction (FNF, FFNFF, FNoF, SNS, NSN). Cyclic voltammetry studies reveal their improved electron affinity compared to oligofluorene. SNS and NSN co-oligomers showed a decrease of their LUMO energies by 0.37–0.38 eV compared to FNF co-oligomer. Absorption/emission studies showed that all oligomers, except FNoF, are blue-emitting materials (λPL ∼ 400–450 nm) with high quantum yields of their photoluminescence (ΦPL = 84–100% in solution and 24–42% in the solid state). FNoF trimer emits in the yellow region with a very low ΦPL ∼ 1% in dichloromethane solution, but the emission efficiency is substantially increased to ΦPL = 10–17% in the solid state. FNF co-oligomer was studied as a metal cation responsive colorimetric and fluorescent sensor using a series of mono- and divalent cations and it showed high sensitivity and selectivity toward mercury cations. Upon addition of Hg2+, the blue emission of FNF (λPL = 404 nm) was quenched and a new, bathochromically shifted (to the green region, λPL = 507 nm) emission band appeared, which allows this compound to be used as both an “ON → OFF” and “OFF → ON” fluorescent sensor.

AB - A series of 4,5-diazafluorene-based (N) conjugated co-oligomers with 9,9-dialkylfluorene (F) or electron-deficient dibenzothiophene-S,S-dioxide (S) has been synthesized by Pd-catalyzed coupling reaction (FNF, FFNFF, FNoF, SNS, NSN). Cyclic voltammetry studies reveal their improved electron affinity compared to oligofluorene. SNS and NSN co-oligomers showed a decrease of their LUMO energies by 0.37–0.38 eV compared to FNF co-oligomer. Absorption/emission studies showed that all oligomers, except FNoF, are blue-emitting materials (λPL ∼ 400–450 nm) with high quantum yields of their photoluminescence (ΦPL = 84–100% in solution and 24–42% in the solid state). FNoF trimer emits in the yellow region with a very low ΦPL ∼ 1% in dichloromethane solution, but the emission efficiency is substantially increased to ΦPL = 10–17% in the solid state. FNF co-oligomer was studied as a metal cation responsive colorimetric and fluorescent sensor using a series of mono- and divalent cations and it showed high sensitivity and selectivity toward mercury cations. Upon addition of Hg2+, the blue emission of FNF (λPL = 404 nm) was quenched and a new, bathochromically shifted (to the green region, λPL = 507 nm) emission band appeared, which allows this compound to be used as both an “ON → OFF” and “OFF → ON” fluorescent sensor.

U2 - 10.1039/C7TC05051H

DO - 10.1039/C7TC05051H

M3 - Article

VL - 6

SP - 3762

EP - 3773

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

SN - 2050-7526

IS - 14

ER -