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Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers

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Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers. / Blayney, A.J.; Perepichka, I.F.; Wuld, F. et al.
In: Israel Journal of Chemistry, Vol. 54, No. 5-6, 23.06.2014, p. 674-688.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Blayney, AJ, Perepichka, IF, Wuld, F & Perepichka, DF 2014, 'Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers', Israel Journal of Chemistry, vol. 54, no. 5-6, pp. 674-688. https://doi.org/10.1002/ijch.201400067

APA

Blayney, A. J., Perepichka, I. F., Wuld, F., & Perepichka, D. F. (2014). Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers. Israel Journal of Chemistry, 54(5-6), 674-688. https://doi.org/10.1002/ijch.201400067

CBE

Blayney AJ, Perepichka IF, Wuld F, Perepichka DF. 2014. Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers. Israel Journal of Chemistry. 54(5-6):674-688. https://doi.org/10.1002/ijch.201400067

MLA

Blayney, A.J. et al. "Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers". Israel Journal of Chemistry. 2014, 54(5-6). 674-688. https://doi.org/10.1002/ijch.201400067

VancouverVancouver

Blayney AJ, Perepichka IF, Wuld F, Perepichka DF. Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers. Israel Journal of Chemistry. 2014 Jun 23;54(5-6):674-688. doi: 10.1002/ijch.201400067

Author

Blayney, A.J. ; Perepichka, I.F. ; Wuld, F. et al. / Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers. In: Israel Journal of Chemistry. 2014 ; Vol. 54, No. 5-6. pp. 674-688.

RIS

TY - JOUR

T1 - Advances and Challenges in the Synthesis of Poly(p-phenylene vinylene)-Based Polymers

AU - Blayney, A.J.

AU - Perepichka, I.F.

AU - Wuld, F.

AU - Perepichka, D.F.

PY - 2014/6/23

Y1 - 2014/6/23

N2 - We provide an overview of the current progress in the synthesis of poly(p-phenylene vinylene) (PPV) polymers. The described synthetic approaches can be divided into four main categories: polymerization of quinodimethane intermediates, metathesis polymerization, nucleophilic polycondensation, and palladium-catalyzed cross-coupling. While such variety is remarkable and very high-molecular-weight PPV can be prepared by some methods, the synthetic chemistry of PPV still limits the structural variety and purity of arylene vinylene polymers. In particular, palladium-catalyzed cross-coupling reactions, the method of choice in the contemporary conjugated polymer chemistry, often shows limited success in PPV series. On the other hand, the possibility of using metathesis polymerization creates new opportunities not available for other classes of conjugated polymers.

AB - We provide an overview of the current progress in the synthesis of poly(p-phenylene vinylene) (PPV) polymers. The described synthetic approaches can be divided into four main categories: polymerization of quinodimethane intermediates, metathesis polymerization, nucleophilic polycondensation, and palladium-catalyzed cross-coupling. While such variety is remarkable and very high-molecular-weight PPV can be prepared by some methods, the synthetic chemistry of PPV still limits the structural variety and purity of arylene vinylene polymers. In particular, palladium-catalyzed cross-coupling reactions, the method of choice in the contemporary conjugated polymer chemistry, often shows limited success in PPV series. On the other hand, the possibility of using metathesis polymerization creates new opportunities not available for other classes of conjugated polymers.

U2 - 10.1002/ijch.201400067

DO - 10.1002/ijch.201400067

M3 - Article

VL - 54

SP - 674

EP - 688

JO - Israel Journal of Chemistry

JF - Israel Journal of Chemistry

SN - 0021-2148

IS - 5-6

ER -