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Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers

Research output: Contribution to journal › Article › peer-review

Standard Standard

Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers. / Anizelli, Helder Scapin; David, Tudur Wyn; Tyagi, Priyanka et al.
In: Solar Energy, Vol. 203, 06.2020, p. 157-163.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Anizelli, HS, David, TW, Tyagi, P, Laureto, E & Kettle, J 2020, 'Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers', Solar Energy, vol. 203, pp. 157-163. https://doi.org/10.1016/j.solener.2020.04.035

APA

Anizelli, H. S., David, T. W., Tyagi, P., Laureto, E., & Kettle, J. (2020). Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers. Solar Energy, 203, 157-163. https://doi.org/10.1016/j.solener.2020.04.035

CBE

Anizelli HS, David TW, Tyagi P, Laureto E, Kettle J. 2020. Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers. Solar Energy. 203:157-163. https://doi.org/10.1016/j.solener.2020.04.035

MLA

Anizelli, Helder Scapin et al. "Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers". Solar Energy. 2020, 203. 157-163. https://doi.org/10.1016/j.solener.2020.04.035

VancouverVancouver

Anizelli HS, David TW, Tyagi P, Laureto E, Kettle J. Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers. Solar Energy. 2020 Jun;203:157-163. Epub 2020 Apr 21. doi: 10.1016/j.solener.2020.04.035

Author

Anizelli, Helder Scapin ; David, Tudur Wyn ; Tyagi, Priyanka et al. / Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers. In: Solar Energy. 2020 ; Vol. 203. pp. 157-163.

RIS

TY - JOUR

T1 - Enhancing the stability of perovskite solar cells through functionalisation of metal oxide transport layers with self-assembled monolayers

AU - Anizelli, Helder Scapin

AU - David, Tudur Wyn

AU - Tyagi, Priyanka

AU - Laureto, Edson

AU - Kettle, Jeffrey

PY - 2020/6

Y1 - 2020/6

N2 - A systematic study of the application of self-assembly monolayers (SAMs) onto electron and hole transporting layers for perovskite solar cells (PSCs) stability is reported. Cs0.05FA0.83MA0.17Pb(I0.87Br0.13)3 (FMC) perovskite films were deposited onto tin oxide (SnO2) and nickel oxide (NiOx) layers that were functionalized with ethylphosphonic acid (EPA) and 4-bromobenzoic acid (BBA) SAMs. X-ray diffractometry measurements were performed on these films shortly after they were deposited. The diffractograms agree with the positions reported in the literature for the crystal structure of the FMC. The results show that the deposition of SAMs on the metal oxide layers yields positive improvements in the FMC film stability and in the device stability when using FMC as the active layer. The work shows that by adopting SAMs, the long-term stability of PSCs cells under accelerated test conditions can be enhanced, and this provides one step on the way to making this technology a commercial reality

AB - A systematic study of the application of self-assembly monolayers (SAMs) onto electron and hole transporting layers for perovskite solar cells (PSCs) stability is reported. Cs0.05FA0.83MA0.17Pb(I0.87Br0.13)3 (FMC) perovskite films were deposited onto tin oxide (SnO2) and nickel oxide (NiOx) layers that were functionalized with ethylphosphonic acid (EPA) and 4-bromobenzoic acid (BBA) SAMs. X-ray diffractometry measurements were performed on these films shortly after they were deposited. The diffractograms agree with the positions reported in the literature for the crystal structure of the FMC. The results show that the deposition of SAMs on the metal oxide layers yields positive improvements in the FMC film stability and in the device stability when using FMC as the active layer. The work shows that by adopting SAMs, the long-term stability of PSCs cells under accelerated test conditions can be enhanced, and this provides one step on the way to making this technology a commercial reality

U2 - 10.1016/j.solener.2020.04.035

DO - 10.1016/j.solener.2020.04.035

M3 - Article

VL - 203

SP - 157

EP - 163

JO - Solar Energy

JF - Solar Energy

SN - 0038-092X

ER -