How the Surface Structure Determines the Properties of CuH
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In: Inorganic Chemistry, Vol. 54, No. 5, 11.02.2015, p. 2213-2220.
Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - How the Surface Structure Determines the Properties of CuH
AU - Bennett, E.L.
AU - Bennett, E.
AU - Wilson, T.
AU - Murphy, P.J.
AU - Refson, K.
AU - Hannon, A.C.
AU - Imberti, S.
AU - Callear, S.K.
AU - Chass, G.A.
AU - Parker, S.F.
PY - 2015/2/11
Y1 - 2015/2/11
N2 - CuH occurs in fields ranging from catalysis to electrochemistry to organic synthesis. We show that, while both aqueous and nonaqueous methods for the synthesis of CuH result in the same bulk product, the surface properties differ: bonded hydroxyls from aqueous routes and a coordinated donor from nonaqueous routes. This work provides a particularly clear example of how the nature of an adsorbed layer on a nanoparticle surface determines the properties
AB - CuH occurs in fields ranging from catalysis to electrochemistry to organic synthesis. We show that, while both aqueous and nonaqueous methods for the synthesis of CuH result in the same bulk product, the surface properties differ: bonded hydroxyls from aqueous routes and a coordinated donor from nonaqueous routes. This work provides a particularly clear example of how the nature of an adsorbed layer on a nanoparticle surface determines the properties
U2 - 10.1021/ic5027009
DO - 10.1021/ic5027009
M3 - Article
VL - 54
SP - 2213
EP - 2220
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 5
ER -