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Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide

Research output: Contribution to journal › Article › peer-review

Standard Standard

Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide. / Marriott, R.J.; Marriott, R.; Sin, E. et al.
In: Comptes Rendus Chimie, Vol. 17, No. 3, 27.01.2014, p. 293-300.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Marriott, RJ, Marriott, R, Sin, E, Hunt, A & Clark, H 2014, 'Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide', Comptes Rendus Chimie, vol. 17, no. 3, pp. 293-300. https://doi.org/10.1016/j.crci.2013.12.001

APA

Marriott, R. J., Marriott, R., Sin, E., Hunt, A., & Clark, H. (2014). Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide. Comptes Rendus Chimie, 17(3), 293-300. https://doi.org/10.1016/j.crci.2013.12.001

CBE

Marriott RJ, Marriott R, Sin E, Hunt A, Clark H. 2014. Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide. Comptes Rendus Chimie. 17(3):293-300. https://doi.org/10.1016/j.crci.2013.12.001

MLA

Marriott, R.J. et al. "Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide". Comptes Rendus Chimie. 2014, 17(3). 293-300. https://doi.org/10.1016/j.crci.2013.12.001

VancouverVancouver

Marriott RJ, Marriott R, Sin E, Hunt A, Clark H. Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide. Comptes Rendus Chimie. 2014 Jan 27;17(3):293-300. doi: 10.1016/j.crci.2013.12.001

Author

Marriott, R.J. ; Marriott, R. ; Sin, E. et al. / Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide. In: Comptes Rendus Chimie. 2014 ; Vol. 17, No. 3. pp. 293-300.

RIS

TY - JOUR

T1 - Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide

AU - Marriott, R.J.

AU - Marriott, R.

AU - Sin, E.

AU - Hunt, A.

AU - Clark, H.

PY - 2014/1/27

Y1 - 2014/1/27

N2 - Supercritical carbon dioxide (scCO2) can be used as a “green” selective solvent for extractions of wheat straw waxes. For the first time, the crude extraction yields of wheat straw waxes and the yields of a single high value group of components (wax esters) using various scCO2 conditions (305.15 to 373.15 K and 7.5 to 40 MPa) have been modelled using the Chrastil equation (Chrastil, 1982). The model accurately predicts both the crude yield and percentage of valuable wax esters within the extracts enabling maximum extraction efficiency. The key compounds within the waxes (fatty acids, sterols, fatty alcohols, wax esters, β-diketones and alkanes) have been identified and quantified. This study highlighted that, 14,16 hentriacontanedione was extracted at critical temperature and pressure in concentrations of 1000 μg.g−1 straw. This molecule could demonstrate significant potential as a natural chelate for metal recovery and also in the formation of super-hydrophobic coatings.

AB - Supercritical carbon dioxide (scCO2) can be used as a “green” selective solvent for extractions of wheat straw waxes. For the first time, the crude extraction yields of wheat straw waxes and the yields of a single high value group of components (wax esters) using various scCO2 conditions (305.15 to 373.15 K and 7.5 to 40 MPa) have been modelled using the Chrastil equation (Chrastil, 1982). The model accurately predicts both the crude yield and percentage of valuable wax esters within the extracts enabling maximum extraction efficiency. The key compounds within the waxes (fatty acids, sterols, fatty alcohols, wax esters, β-diketones and alkanes) have been identified and quantified. This study highlighted that, 14,16 hentriacontanedione was extracted at critical temperature and pressure in concentrations of 1000 μg.g−1 straw. This molecule could demonstrate significant potential as a natural chelate for metal recovery and also in the formation of super-hydrophobic coatings.

U2 - 10.1016/j.crci.2013.12.001

DO - 10.1016/j.crci.2013.12.001

M3 - Article

VL - 17

SP - 293

EP - 300

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

SN - 1631-0748

IS - 3

ER -