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Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures

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Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures. / Fugu, Mohammed B.; Ellaby, Rebecca J.; O`Connor, Helen M. et al.
In: Dalton Transactions, Vol. 48, No. 27, 07.2019, p. 10180-10190.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Fugu, MB, Ellaby, RJ, O`Connor, HM, Pitak, MB, Klooster , W, Horton, PN, Coles, SJ, Al-mashhadani, MH, Brechin, EK, Perepichka, I & Jones, LF 2019, 'Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures', Dalton Transactions, vol. 48, no. 27, pp. 10180-10190. https://doi.org/10.1039/C9DT01531K

APA

Fugu, M. B., Ellaby, R. J., O`Connor, H. M., Pitak, M. B., Klooster , W., Horton, P. N., Coles, S. J., Al-mashhadani, M. H., Brechin, E. K., Perepichka, I., & Jones, L. F. (2019). Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures. Dalton Transactions, 48(27), 10180-10190. https://doi.org/10.1039/C9DT01531K

CBE

Fugu MB, Ellaby RJ, O`Connor HM, Pitak MB, Klooster W, Horton PN, Coles SJ, Al-mashhadani MH, Brechin EK, Perepichka I, et al. 2019. Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures. Dalton Transactions. 48(27):10180-10190. https://doi.org/10.1039/C9DT01531K

MLA

Fugu, Mohammed B. et al. "Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures". Dalton Transactions. 2019, 48(27). 10180-10190. https://doi.org/10.1039/C9DT01531K

VancouverVancouver

Fugu MB, Ellaby RJ, O`Connor HM, Pitak MB, Klooster W, Horton PN et al. Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures. Dalton Transactions. 2019 Jul;48(27):10180-10190. Epub 2019 Jun 4. doi: 10.1039/C9DT01531K

Author

Fugu, Mohammed B. ; Ellaby, Rebecca J. ; O`Connor, Helen M. et al. / Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures. In: Dalton Transactions. 2019 ; Vol. 48, No. 27. pp. 10180-10190.

RIS

TY - JOUR

T1 - Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures

AU - Fugu, Mohammed B.

AU - Ellaby, Rebecca J.

AU - O`Connor, Helen M.

AU - Pitak, Mateusz B.

AU - Klooster , Wim

AU - Horton, Peter N.

AU - Coles, Simon J.

AU - Al-mashhadani, Mohammed H.

AU - Brechin, Euan K.

AU - Perepichka, Igor

AU - Jones, Leigh F.

PY - 2019/7

Y1 - 2019/7

N2 - A family of mono- and ditopic hydroxamic acids have been employed in the synthesis, structural and physical characterisation of discrete (0D) and (1- and 2-D) extended network coordination complexes. Examples of the latter include the 1-D coordination polymer {[Zn(II)(L3H)2]·2MeOH}n (5; L3H2 = 2-(methylamino)phenylhydroxamic acid) and the 2-D extended network {[Cu(II)(L2H)(H2O)(NO3)]·H2O}n (5; L2H2 = 4-amino-2-(acetoxy)phenylhydroxamic acid). The 12-MC-4 metallacrown [Cu(II)5(L4H)4(MeOH)2(NO3)2]·3H2O.4MeOH (7) represents the first metal complex constructed using the novel ligand N-hydroxy-2-[(2-hydroxy-3-methoxybenzyl)amino]benzamide (L4H3). Variable temperature magnetic susceptibility studies confirm strong antiferromagnetic exchange between the Cu(II) centres in 7. Coordination polymer 5 shows photoluminescence in the blue region (λPL ~ 421 – 450 nm) with a bathochromic shift of the emission (~ 15 – 30 nm) from solution to the solid state.

AB - A family of mono- and ditopic hydroxamic acids have been employed in the synthesis, structural and physical characterisation of discrete (0D) and (1- and 2-D) extended network coordination complexes. Examples of the latter include the 1-D coordination polymer {[Zn(II)(L3H)2]·2MeOH}n (5; L3H2 = 2-(methylamino)phenylhydroxamic acid) and the 2-D extended network {[Cu(II)(L2H)(H2O)(NO3)]·H2O}n (5; L2H2 = 4-amino-2-(acetoxy)phenylhydroxamic acid). The 12-MC-4 metallacrown [Cu(II)5(L4H)4(MeOH)2(NO3)2]·3H2O.4MeOH (7) represents the first metal complex constructed using the novel ligand N-hydroxy-2-[(2-hydroxy-3-methoxybenzyl)amino]benzamide (L4H3). Variable temperature magnetic susceptibility studies confirm strong antiferromagnetic exchange between the Cu(II) centres in 7. Coordination polymer 5 shows photoluminescence in the blue region (λPL ~ 421 – 450 nm) with a bathochromic shift of the emission (~ 15 – 30 nm) from solution to the solid state.

U2 - 10.1039/C9DT01531K

DO - 10.1039/C9DT01531K

M3 - Article

VL - 48

SP - 10180

EP - 10190

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 27

ER -