Electronic versions

Documents

DOI

We extend our recent quantum dynamical study of the exciton dissociation and charge transfer at an oligothiophene–fullerene heterojunction interface (Tamura et al., 2012) [6] by investigating the process using the non-perturbative hierarchical equations of motion (HEOM) approach. Based upon an effective mode reconstruction of the spectral density the effect of temperature on the charge transfer is studied using reduced density matrices. It was found that the temperature had little effect on the charge transfer and a coherent dynamics persists over the first few tens of femtoseconds, indicating that the primary charge transfer step proceeds by an activationless pathway.
Original languageEnglish
Pages (from-to)111-118
JournalChemical Physics
Volume442
DOIs
Publication statusPublished - 9 Jul 2014

Total downloads

No data available
View graph of relations