On the stoichiometry of zirconium carbide

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On the stoichiometry of zirconium carbide. / Gasparrini, Claudia; Rana, Dhan-sham; Le Brun, Niccolò et al.
In: Scientific Reports, Vol. 10, No. 1, 14.04.2020, p. 6347.

Research output: Contribution to journalArticlepeer-review

HarvardHarvard

Gasparrini, C, Rana, D, Le Brun, N, Horlait, D, Markides, CN, Farnan, I & Lee, WE 2020, 'On the stoichiometry of zirconium carbide', Scientific Reports, vol. 10, no. 1, pp. 6347. https://doi.org/10.1038/s41598-020-63037-0

APA

Gasparrini, C., Rana, D., Le Brun, N., Horlait, D., Markides, C. N., Farnan, I., & Lee, W. E. (2020). On the stoichiometry of zirconium carbide. Scientific Reports, 10(1), 6347. https://doi.org/10.1038/s41598-020-63037-0

CBE

Gasparrini C, Rana D, Le Brun N, Horlait D, Markides CN, Farnan I, Lee WE. 2020. On the stoichiometry of zirconium carbide. Scientific Reports. 10(1):6347. https://doi.org/10.1038/s41598-020-63037-0

MLA

Gasparrini, Claudia et al. "On the stoichiometry of zirconium carbide". Scientific Reports. 2020, 10(1). 6347. https://doi.org/10.1038/s41598-020-63037-0

VancouverVancouver

Gasparrini C, Rana D, Le Brun N, Horlait D, Markides CN, Farnan I et al. On the stoichiometry of zirconium carbide. Scientific Reports. 2020 Apr 14;10(1):6347. doi: 10.1038/s41598-020-63037-0

Author

Gasparrini, Claudia ; Rana, Dhan-sham ; Le Brun, Niccolò et al. / On the stoichiometry of zirconium carbide. In: Scientific Reports. 2020 ; Vol. 10, No. 1. pp. 6347.

RIS

TY - JOUR

T1 - On the stoichiometry of zirconium carbide

AU - Gasparrini, Claudia

AU - Rana, Dhan-sham

AU - Le Brun, Niccolò

AU - Horlait, Denis

AU - Markides, Christos N.

AU - Farnan, Ian

AU - Lee, William E.

PY - 2020/4/14

Y1 - 2020/4/14

N2 - Abstract: The dependencies of the enhanced thermomechanical properties of zirconium carbide (ZrCx) with sample purity and stoichiometry are still not understood due to discrepancies in the literature. Multiple researchers have recently reported a linear relation between the carbon to zirconium atomic ratio (C/Zr) and the lattice parameter, in contrast with a more established relationship that suggests that the lattice parameter value attains a maximum value at a C/Zr ~ 0.83. In this study, the relationship between C/Zr atomic ratio and the lattice parameter is critically assessed: it is found that recent studies reporting the thermophysical properties of ZrCx have unintentionally produced and characterised samples containing zirconium oxycarbide. To avoid such erroneous characterization of ZrCx thermophysical properties in the future, we propose a method for the accurate measurement of the stoichiometry of ZrCx using three independent experimental techniques, namely: elemental analysis, thermogravimetric analysis and nuclear magnetic resonance spectroscopy. Although a large scatter in the results (ΔC/Zr = 0.07) from these different techniques was found when used independently, when combining the techniques together consistent values of x in ZrCx were obtained.

AB - Abstract: The dependencies of the enhanced thermomechanical properties of zirconium carbide (ZrCx) with sample purity and stoichiometry are still not understood due to discrepancies in the literature. Multiple researchers have recently reported a linear relation between the carbon to zirconium atomic ratio (C/Zr) and the lattice parameter, in contrast with a more established relationship that suggests that the lattice parameter value attains a maximum value at a C/Zr ~ 0.83. In this study, the relationship between C/Zr atomic ratio and the lattice parameter is critically assessed: it is found that recent studies reporting the thermophysical properties of ZrCx have unintentionally produced and characterised samples containing zirconium oxycarbide. To avoid such erroneous characterization of ZrCx thermophysical properties in the future, we propose a method for the accurate measurement of the stoichiometry of ZrCx using three independent experimental techniques, namely: elemental analysis, thermogravimetric analysis and nuclear magnetic resonance spectroscopy. Although a large scatter in the results (ΔC/Zr = 0.07) from these different techniques was found when used independently, when combining the techniques together consistent values of x in ZrCx were obtained.

KW - Article

KW - /639/638/263/915

KW - /639/4077/4091/4093

KW - /639/301/299

KW - /128

KW - /145

KW - /140/131

KW - article

U2 - 10.1038/s41598-020-63037-0

DO - 10.1038/s41598-020-63037-0

M3 - Article

VL - 10

SP - 6347

JO - Scientific Reports

JF - Scientific Reports

SN - 2045-2322

IS - 1

ER -