Predicted pyrochlore to fluorite disorder temperature for A(2)Zr(2)O(7) compositions
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In a previous publication the order-disorder pyrochlore to fluorite transformation temperatures for a series of A(2)Hf(2)O(7) pyrochlores were predicted [C.R. Stanek and R.W. Grimes: Prediction of rare-earth A(2)Hf(2)O(7), pyrochlore phases. J. Am. Ceram. Soc. 2002, 85, p. 2139]. This was facilitated by establishing a relationship between these temperatures and the energy required to introduce a specific defect structure into the perfect pyrochlore lattice. Here an equivalent relationship for A(2)Zr(2)O(7) pyrochlores was generated, and from this the disorder temperatures for a number of compositions including Eu2Zr2O7 were predicted.
| Original language | Unknown |
|---|---|
| Pages (from-to) | 1603-1604 |
| Number of pages | 2 |
| Journal | Journal of Materials Research |
| Volume | 19 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 1 Jun 2004 |
| Externally published | Yes |