Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system
Research output: Contribution to journal › Article › peer-review
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- TL 2013
Accepted author manuscript, 461 KB, PDF document
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DOI
Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated.
| Original language | English |
|---|---|
| Pages (from-to) | 1227-1229 |
| Journal | Tetrahedron Letters |
| Volume | 54 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 6 Mar 2013 |
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