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Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks.

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Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks. / Houton, Edel; Comar, Priyanka; Pitak, Mateusz B. et al.
In: RSC Advances, No. 77, 28.07.2016, p. 73668-73676.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Houton, E, Comar, P, Pitak, MB, Coles, SJ, Ryder, AG, Piligkos, S, Brechin, EK & Jones, L 2016, 'Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks.', RSC Advances, no. 77, pp. 73668-73676. https://doi.org/10.1039/x0xx00000x

APA

Houton, E., Comar, P., Pitak, M. B., Coles, S. J., Ryder, A. G., Piligkos, S., Brechin, E. K., & Jones, L. (2016). Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks. RSC Advances, (77), 73668-73676. https://doi.org/10.1039/x0xx00000x

CBE

Houton E, Comar P, Pitak MB, Coles SJ, Ryder AG, Piligkos S, Brechin EK, Jones L. 2016. Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks. RSC Advances. (77):73668-73676. https://doi.org/10.1039/x0xx00000x

MLA

Houton, Edel et al. "Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks.". RSC Advances. 2016, (77). 73668-73676. https://doi.org/10.1039/x0xx00000x

VancouverVancouver

Houton E, Comar P, Pitak MB, Coles SJ, Ryder AG, Piligkos S et al. Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks. RSC Advances. 2016 Jul 28;(77):73668-73676. doi: 10.1039/x0xx00000x

Author

Houton, Edel ; Comar, Priyanka ; Pitak, Mateusz B. et al. / Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks. In: RSC Advances. 2016 ; No. 77. pp. 73668-73676.

RIS

TY - JOUR

T1 - Solvothermal Synthesis of Discrete Cages and Extended Networks Comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) Building Blocks.

AU - Houton, Edel

AU - Comar, Priyanka

AU - Pitak, Mateusz B.

AU - Coles, Simon J.

AU - Ryder, Alan G.

AU - Piligkos, Stergios

AU - Brechin, Euan K.

AU - Jones, Leigh

N1 - SFI Investigator Program for funding (Investigator Project Number: 12/IP/1322); IRCSET Embark Fellowship Program

PY - 2016/7/28

Y1 - 2016/7/28

N2 - The synthesis, structural and magnetic characterisation of a family of related Cr(III) cages are reported. Each member comprises {Cr(III)3O(O2CR1)3(R2-sao)3}2- (R1 = H, CH3, C(CH3)3, C14H9 ; R2 = Me, Ph, tBu, C10H8) triangles linked by Na+ cations, resulting in either the discrete complexes [H3O][NEt4]2[NaCr(III)6O2(O2C-C14H9)6(Naphth-sao)6] (1) and [Na4Cr(III)6O2(O2CC(CH3)3)6(3,5-di-tBu-sao)6(MeCN)6] (3); or the extended networks [H3O]2[Na2Cr(III)6O2(O2CH)6(Ph-sao)6(MeCN)2(H2O)2]n·4MeCN (2); [H3O][Na3Cr(III)6O2(O2CCH3)6(Me-sao)6(MeCN)]n (4) and [Na2Cr(III)3O(O2CCH3)3(Me-sao)3(H2O)6]n·3MeCN (5). Magnetic susceptibility data obtained for 2 and 4 reveal weak antiferromagnetic exchange between the Cr(III) ions in the triangles.

AB - The synthesis, structural and magnetic characterisation of a family of related Cr(III) cages are reported. Each member comprises {Cr(III)3O(O2CR1)3(R2-sao)3}2- (R1 = H, CH3, C(CH3)3, C14H9 ; R2 = Me, Ph, tBu, C10H8) triangles linked by Na+ cations, resulting in either the discrete complexes [H3O][NEt4]2[NaCr(III)6O2(O2C-C14H9)6(Naphth-sao)6] (1) and [Na4Cr(III)6O2(O2CC(CH3)3)6(3,5-di-tBu-sao)6(MeCN)6] (3); or the extended networks [H3O]2[Na2Cr(III)6O2(O2CH)6(Ph-sao)6(MeCN)2(H2O)2]n·4MeCN (2); [H3O][Na3Cr(III)6O2(O2CCH3)6(Me-sao)6(MeCN)]n (4) and [Na2Cr(III)3O(O2CCH3)3(Me-sao)3(H2O)6]n·3MeCN (5). Magnetic susceptibility data obtained for 2 and 4 reveal weak antiferromagnetic exchange between the Cr(III) ions in the triangles.

U2 - 10.1039/x0xx00000x

DO - 10.1039/x0xx00000x

M3 - Article

SP - 73668

EP - 73676

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 77

ER -