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Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes

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Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes. / Rigby, Maxwell T. P.; Natu, Varun; Sokol, Maxim et al.
In: RSC Advances, Vol. 11, No. 5, 22.01.2021.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Rigby, MTP, Natu, V, Sokol, M, Kelly, DJ, Hopkinson, DG, Zou, Y, Bird, JRT, Evitts, LJ, Smith, M, Race, CP, Frankel, P, Haigh, SJ & Barsoum, MW 2021, 'Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes', RSC Advances, vol. 11, no. 5. https://doi.org/10.1039/D0RA09761F

APA

Rigby, M. T. P., Natu, V., Sokol, M., Kelly, D. J., Hopkinson, D. G., Zou, Y., Bird, J. R. T., Evitts, L. J., Smith, M., Race, C. P., Frankel, P., Haigh, S. J., & Barsoum, M. W. (2021). Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes. RSC Advances, 11(5). https://doi.org/10.1039/D0RA09761F

CBE

Rigby MTP, Natu V, Sokol M, Kelly DJ, Hopkinson DG, Zou Y, Bird JRT, Evitts LJ, Smith M, Race CP, et al. 2021. Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes. RSC Advances. 11(5). https://doi.org/10.1039/D0RA09761F

MLA

Rigby, Maxwell T. P. et al. "Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes". RSC Advances. 2021. 11(5). https://doi.org/10.1039/D0RA09761F

VancouverVancouver

Rigby MTP, Natu V, Sokol M, Kelly DJ, Hopkinson DG, Zou Y et al. Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes. RSC Advances. 2021 Jan 22;11(5). Epub 2021 Jan 13. doi: https://doi.org/10.1039/D0RA09761F

Author

Rigby, Maxwell T. P. ; Natu, Varun ; Sokol, Maxim et al. / Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes. In: RSC Advances. 2021 ; Vol. 11, No. 5.

RIS

TY - JOUR

T1 - Synthesis of new M-layer solid-solution 312 MAX phases (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes

AU - Rigby, Maxwell T. P.

AU - Natu, Varun

AU - Sokol, Maxim

AU - Kelly, Daniel J.

AU - Hopkinson, David G.

AU - Zou, Yichao

AU - Bird, James R. T.

AU - Evitts, Lee J.

AU - Smith, Matt

AU - Race, Christopher P.

AU - Frankel, Philipp

AU - Haigh, Sarah J.

AU - Barsoum, Michel W.

PY - 2021/1/22

Y1 - 2021/1/22

N2 - Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.

AB - Quaternary MAX phases, (Ta1−xTix)3AlC2 (x = 0.4, 0.62, 0.75, 0.91 or 0.95), have been synthesised via pressureless sintering of TaC, TiC, Ti and Al powders. Via chemical etching of the Al layers, (Ta0.38Ti0.62)3C2Tz – a new MXene, has also been synthesised. All materials contain an M-layer solid solution of Ta and Ti, with a variable Ta concentration, paving the way for the synthesis of a range of alloyed (Ta,Ti)3C2Tz MXenes with tuneable compositions for a wide range of potential applications.

U2 - https://doi.org/10.1039/D0RA09761F

DO - https://doi.org/10.1039/D0RA09761F

M3 - Article

VL - 11

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 5

ER -