The cycloaddition of cyclopropenes to enones
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In: Tetrahedron Letters, Vol. 41, No. 21, 29.05.2000, p. 4205-4208.
Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - The cycloaddition of cyclopropenes to enones
AU - Al Dulayymi, JR
AU - Baird, MS
AU - Hussain, HH
AU - Alhourani, BJ
AU - Alhabashna, AMY
AU - Coles, SJ
AU - Hursthouse, MB
PY - 2000/5/29
Y1 - 2000/5/29
N2 - A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.
AB - A number of 1- and 1,2-disubstituted cyclopropenes undergo [4+2]-cycloaddition to methyl vinyl ketone or acrolein at ambient temperature to produce 2-oxabicyclo[4.1.0]hept-3-enes. When 1-phenyl-2-trimethylsilyl cyclopropene is treated with 0.4 mel. equiv. of m-chloroperbenzoic acid, the derived ring-opened enone undergoes [4+2]-cycloaddition to the remaining starting material at ambient temperature. (C) 2000 Elsevier Science Ltd. All rights reserved.
U2 - 10.1016/S0040-4039(00)00566-9
DO - 10.1016/S0040-4039(00)00566-9
M3 - Article
VL - 41
SP - 4205
EP - 4208
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 21
ER -