Viscosity bounds in liquids with different structure and bonding types
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In: Physical Review B , Vol. 109, 094205, 19.03.2024.
Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Viscosity bounds in liquids with different structure and bonding types
AU - Whittington, M.
AU - Devereux, H. L.
AU - Cockrell, Cillian
AU - Elena, A. M.
AU - Todorov, I. T.
AU - Liu, K.
AU - Shang, S. L.
AU - McCloy, J. S.
AU - Bingham, P. A.
AU - Trachenko, K.
PY - 2024/3/19
Y1 - 2024/3/19
N2 - Recently, it was realized that liquid viscosity has a lower bound which is nearly constant for all liquids and is governed by fundamental physical constants. This was supported by experimental data in noble and molecular liquids. Here, we perform large-scale molecular dynamics simulations to ascertain this bound in two other important liquid types: the ionic molten salt system LiF and metallic Pb. We find that these ionic and metallic systems similarly have lower viscosity bounds corresponding to the minimum of kinematic viscosity of ∼10−7m2/s. We show that this agrees with experimental data in other systems with different structures and bonding types, including noble, molecular, metallic, and covalent liquids. This expands the universality of viscosity bounds into the main system types known
AB - Recently, it was realized that liquid viscosity has a lower bound which is nearly constant for all liquids and is governed by fundamental physical constants. This was supported by experimental data in noble and molecular liquids. Here, we perform large-scale molecular dynamics simulations to ascertain this bound in two other important liquid types: the ionic molten salt system LiF and metallic Pb. We find that these ionic and metallic systems similarly have lower viscosity bounds corresponding to the minimum of kinematic viscosity of ∼10−7m2/s. We show that this agrees with experimental data in other systems with different structures and bonding types, including noble, molecular, metallic, and covalent liquids. This expands the universality of viscosity bounds into the main system types known
U2 - 10.1103/PhysRevB.109.094205
DO - 10.1103/PhysRevB.109.094205
M3 - Article
VL - 109
JO - Physical Review B
JF - Physical Review B
SN - 2469-9950
M1 - 094205
ER -