A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
Fersiynau electronig
Dangosydd eitem ddigidol (DOI)
The synthesis and XRD structure of
[Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported.
Compound 1 arises through a selective templating process
from a DCL of polyborate anions. Compound 1 contains two
different polyborate species with [B8O10(OH)6]2- being particularly
novel. It is comprised of a fused tetraborate and pentaborate
anions with a 4-coordinate B atom and a 3 coordinate
O atom in common.
| Iaith wreiddiol | Saesneg |
|---|---|
| Tudalennau (o-i) | 412-414 |
| Cyfnodolyn | Inorganic Chemistry |
| Cyfrol | 54 |
| Rhif y cyfnodolyn | 2 |
| Dyddiad ar-lein cynnar | 22 Rhag 2014 |
| Dynodwyr Gwrthrych Digidol (DOIs) | |
| Statws | Cyhoeddwyd - 2015 |