StandardStandard

A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane). / Altahan, M.A.; Beckett, M.A.; Coles, S.J. et al.
Yn: Inorganic Chemistry, Cyfrol 54, Rhif 2, 2015, t. 412-414.

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

HarvardHarvard

APA

CBE

MLA

VancouverVancouver

Author

RIS

TY - JOUR

T1 - A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)

AU - Altahan, M.A.

AU - Beckett, M.A.

AU - Coles, S.J.

AU - Horton, P.N.

PY - 2015

Y1 - 2015

N2 - The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.

AB - The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.

U2 - 10.1021/ic5027834

DO - 10.1021/ic5027834

M3 - Article

VL - 54

SP - 412

EP - 414

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 2

ER -