A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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Yn: Inorganic Chemistry, Cyfrol 54, Rhif 2, 2015, t. 412-414.
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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T1 - A New Decaoxidooctaborate(2-) Anion, [B8O10(OH)(6)}(2-): Synthesis and Characterization of [Co(en)3][B5O6(OH)(4)][B8O10(OH)(6))]center dot 5H(2)O (en=1,2-Diaminoethane)
AU - Altahan, M.A.
AU - Beckett, M.A.
AU - Coles, S.J.
AU - Horton, P.N.
PY - 2015
Y1 - 2015
N2 - The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.
AB - The synthesis and XRD structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6].5H2O (1) is reported. Compound 1 arises through a selective templating process from a DCL of polyborate anions. Compound 1 contains two different polyborate species with [B8O10(OH)6]2- being particularly novel. It is comprised of a fused tetraborate and pentaborate anions with a 4-coordinate B atom and a 3 coordinate O atom in common.
U2 - 10.1021/ic5027834
DO - 10.1021/ic5027834
M3 - Article
VL - 54
SP - 412
EP - 414
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 2
ER -