Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations
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Fersiynau electronig
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- PDB3660-00.pdf
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Dangosydd eitem ddigidol (DOI)
The synthesis and characterization of a series of pentaborate(1−) salts of substituted pyrrolidinium cations [C4H8NH2][B5O6(OH)4] (1), [C4H8NMe2][B5O6(OH)4] (2) [C4H8NMeH][B5O6(OH)4] (3), [(2-CH2OH)C4H7NH2][B5O6(OH)4] (4) is reported. All compounds were characterized by single-crystal XRD studies with 3 (1/2CH3COCH3) and 4 (1/2H2O) solvated. TGA/DSC analysis of the pentaborates 1–4 showed that they thermally decomposed in air at 800 °C to 2.5 B2O3, in a 2 step process involving dehydration (
| Iaith wreiddiol | Saesneg |
|---|---|
| Tudalennau (o-i) | 7032-7040 |
| Cyfnodolyn | Dalton Transactions |
| Cyfrol | 44 |
| Dynodwyr Gwrthrych Digidol (DOIs) | |
| Statws | Cyhoeddwyd - 10 Maw 2015 |
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