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Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations. / Beckett, M.A.; Coles, S.; Davies, R.A. et al.
Yn: Dalton Transactions, Cyfrol 44, 10.03.2015, t. 7032-7040.

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

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T1 - Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations

AU - Beckett, M.A.

AU - Coles, S.

AU - Davies, R.A.

AU - Horton, P.

AU - Jones, C.L.

PY - 2015/3/10

Y1 - 2015/3/10

N2 - The synthesis and characterization of a series of pentaborate(1−) salts of substituted pyrrolidinium cations [C4H8NH2][B5O6(OH)4] (1), [C4H8NMe2][B5O6(OH)4] (2) [C4H8NMeH][B5O6(OH)4] (3), [(2-CH2OH)C4H7NH2][B5O6(OH)4] (4) is reported. All compounds were characterized by single-crystal XRD studies with 3 (1/2CH3COCH3) and 4 (1/2H2O) solvated. TGA/DSC analysis of the pentaborates 1–4 showed that they thermally decomposed in air at 800 °C to 2.5 B2O3, in a 2 step process involving dehydration (

AB - The synthesis and characterization of a series of pentaborate(1−) salts of substituted pyrrolidinium cations [C4H8NH2][B5O6(OH)4] (1), [C4H8NMe2][B5O6(OH)4] (2) [C4H8NMeH][B5O6(OH)4] (3), [(2-CH2OH)C4H7NH2][B5O6(OH)4] (4) is reported. All compounds were characterized by single-crystal XRD studies with 3 (1/2CH3COCH3) and 4 (1/2H2O) solvated. TGA/DSC analysis of the pentaborates 1–4 showed that they thermally decomposed in air at 800 °C to 2.5 B2O3, in a 2 step process involving dehydration (

U2 - 10.1039/C5DT00248F

DO - 10.1039/C5DT00248F

M3 - Article

VL - 44

SP - 7032

EP - 7040

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

ER -