Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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Yn: RSC Advances, Cyfrol 3, 17.06.2013, t. 15185-15191.
Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid
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T1 - Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties
AU - Beckett, M.A.
AU - Horton, P.N.
AU - Hursthouse, M.B.
AU - Timmis, J.L.
PY - 2013/6/17
Y1 - 2013/6/17
N2 - The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (
AB - The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (
U2 - 10.1039/C3RA42387E
DO - 10.1039/C3RA42387E
M3 - Article
VL - 3
SP - 15185
EP - 15191
JO - RSC Advances
JF - RSC Advances
SN - 2046-2069
ER -