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Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties

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Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties. / Beckett, M.A.; Horton, P.N.; Hursthouse, M.B. et al.
In: RSC Advances, Vol. 3, 17.06.2013, p. 15185-15191.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Beckett, MA, Horton, PN, Hursthouse, MB & Timmis, JL 2013, 'Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties', RSC Advances, vol. 3, pp. 15185-15191. https://doi.org/10.1039/C3RA42387E

APA

Beckett, M. A., Horton, P. N., Hursthouse, M. B., & Timmis, J. L. (2013). Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties. RSC Advances, 3, 15185-15191. https://doi.org/10.1039/C3RA42387E

CBE

Beckett MA, Horton PN, Hursthouse MB, Timmis JL. 2013. Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties. RSC Advances. 3:15185-15191. https://doi.org/10.1039/C3RA42387E

MLA

Beckett, M.A. et al. "Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties". RSC Advances. 2013, 3. 15185-15191. https://doi.org/10.1039/C3RA42387E

VancouverVancouver

Beckett MA, Horton PN, Hursthouse MB, Timmis JL. Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties. RSC Advances. 2013 Jun 17;3:15185-15191. doi: 10.1039/C3RA42387E

Author

Beckett, M.A. ; Horton, P.N. ; Hursthouse, M.B. et al. / Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties. In: RSC Advances. 2013 ; Vol. 3. pp. 15185-15191.

RIS

TY - JOUR

T1 - Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties

AU - Beckett, M.A.

AU - Horton, P.N.

AU - Hursthouse, M.B.

AU - Timmis, J.L.

PY - 2013/6/17

Y1 - 2013/6/17

N2 - The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (

AB - The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (

U2 - 10.1039/C3RA42387E

DO - 10.1039/C3RA42387E

M3 - Article

VL - 3

SP - 15185

EP - 15191

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

ER -