This paper describes dynamic mechanical analysis (DMA) experiments on archaeological and contemporary elm tested under air-dry conditions, to explore the suitability of this technique for increasing understanding of the viscoelastic behaviour of archaeological wood. A strong reduction of storage modulus of archaeological elm (AE) was seen in comparison with contemporary wood (CE), resulting from the high degree of wood degradation, notably the reduction in hemicelluloses and cellulose content of AE, as demonstrated by Attenuated Total Reflection-Fourier Transform Infra-Red spectroscopy (ATR-FTIR). The γ relaxation peak was observed in all samples. The γ peak in AE shifted to a higher temperature, and the activation energy for γ-peak motions was lower in AE (29 kJ/mol) than in CE (50 kJ/mol) indicating that motion is less restricted within the degraded AE cell wall, or possibly a difference in the monomer undergoing rotation. Detection of changes in storage modulus are well known, but the DMA temperature scan technique proved to be useful for probing the degree of wood degradation, relating to the changes in location and intensity of secondary relaxation peaks. The γ peak in loss factor can be used to confirm that cell wall degradation is at an advanced stage, and to improve understanding of the internal spatial structure of the degraded wood cell wall.