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Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3.

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Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3. / Altahan, Mohammed A.; Beckett, Michael A.; Coles, Simon J. et al.
In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 194, No. 10, 03.10.2019, p. 948-951.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Altahan, MA, Beckett, MA, Coles, SJ & Horton, PN 2019, 'Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3.', Phosphorus, Sulfur and Silicon and the Related Elements, vol. 194, no. 10, pp. 948-951. https://doi.org/10.1080/10426507.2019.1631307

APA

Altahan, M. A., Beckett, M. A., Coles, S. J., & Horton, P. N. (2019). Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3. Phosphorus, Sulfur and Silicon and the Related Elements, 194(10), 948-951. https://doi.org/10.1080/10426507.2019.1631307

CBE

Altahan MA, Beckett MA, Coles SJ, Horton PN. 2019. Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3. Phosphorus, Sulfur and Silicon and the Related Elements. 194(10):948-951. https://doi.org/10.1080/10426507.2019.1631307

MLA

Altahan, Mohammed A. et al. "Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3.". Phosphorus, Sulfur and Silicon and the Related Elements. 2019, 194(10). 948-951. https://doi.org/10.1080/10426507.2019.1631307

VancouverVancouver

Altahan MA, Beckett MA, Coles SJ, Horton PN. Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3. Phosphorus, Sulfur and Silicon and the Related Elements. 2019 Oct 3;194(10):948-951. Epub 2019 Jun 20. doi: 10.1080/10426507.2019.1631307

Author

Altahan, Mohammed A. ; Beckett, Michael A. ; Coles, Simon J. et al. / Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3. In: Phosphorus, Sulfur and Silicon and the Related Elements. 2019 ; Vol. 194, No. 10. pp. 948-951.

RIS

TY - JOUR

T1 - Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3.

AU - Altahan, Mohammed A.

AU - Beckett, Michael A.

AU - Coles, Simon J.

AU - Horton, Peter N.

N1 - This is an original manuscript of an article published by Taylor & Francis in Phosphorus, Sulfur and Silicon and the Related Elements on 20.06.2019, available online: http://www.tandfonline.com/10.1080/10426507.2019.1631307.

PY - 2019/10/3

Y1 - 2019/10/3

N2 - The pentaborate(1-) salt, [Cu(dmen)2(H2O)2][B5O6(OH)4]2.2B(OH)3(dmen = N,N’-dimethylethylenediamine, MeHNCH2CH2NHMe), has been synthesized in 48% yield as a crystalline product by reaction of B(OH)3 with [Cu(dmen)2](OH)2]2 (10:1 ratio) in aqueous solution. Single-crystal XRD analysis confirms its ionic structure with one interstitial B(OH)3 per pentaborate(1-) unit. The pentaborate(1-) anions and B(OH)3 molecules are involved in a supramolecular giant H-bonded lattice with B(OH)3 units serving as ‘spacers’ to help accommodate the relatively large [Cu(dmen)2(H2O)2]2+ cations

AB - The pentaborate(1-) salt, [Cu(dmen)2(H2O)2][B5O6(OH)4]2.2B(OH)3(dmen = N,N’-dimethylethylenediamine, MeHNCH2CH2NHMe), has been synthesized in 48% yield as a crystalline product by reaction of B(OH)3 with [Cu(dmen)2](OH)2]2 (10:1 ratio) in aqueous solution. Single-crystal XRD analysis confirms its ionic structure with one interstitial B(OH)3 per pentaborate(1-) unit. The pentaborate(1-) anions and B(OH)3 molecules are involved in a supramolecular giant H-bonded lattice with B(OH)3 units serving as ‘spacers’ to help accommodate the relatively large [Cu(dmen)2(H2O)2]2+ cations

KW - Copper(2+) complexes

KW - X-ray structure

KW - boric acid

KW - oxidoborates

KW - pentaborate(1-)

KW - polyborates

U2 - 10.1080/10426507.2019.1631307

DO - 10.1080/10426507.2019.1631307

M3 - Article

VL - 194

SP - 948

EP - 951

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

SN - 1042-6507

IS - 10

ER -