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Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane)

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Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane). / Altahan, Mohammed; Beckett, Michael; Coles, Simon J. et al.
In: Inorganics, Vol. 7, No. 4, 44, 04.2019.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Altahan, M, Beckett, M, Coles, SJ & Horton, PN 2019, 'Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane)', Inorganics, vol. 7, no. 4, 44. https://doi.org/10.3390/inorganics7040044

APA

Altahan, M., Beckett, M., Coles, S. J., & Horton, P. N. (2019). Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane). Inorganics, 7(4), Article 44. https://doi.org/10.3390/inorganics7040044

CBE

Altahan M, Beckett M, Coles SJ, Horton PN. 2019. Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane). Inorganics. 7(4):Article 44. https://doi.org/10.3390/inorganics7040044

MLA

Altahan, Mohammed et al. "Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane)". Inorganics. 2019. 7(4). https://doi.org/10.3390/inorganics7040044

VancouverVancouver

Altahan M, Beckett M, Coles SJ, Horton PN. Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane). Inorganics. 2019 Apr;7(4):44. Epub 2019 Mar 27. doi: 10.3390/inorganics7040044

Author

Altahan, Mohammed ; Beckett, Michael ; Coles, Simon J. et al. / Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane). In: Inorganics. 2019 ; Vol. 7, No. 4.

RIS

TY - JOUR

T1 - Hexaborate(2-) and Dodecaborate(6-) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{O-3-B6O7(OH)(6)}(N-3-dien)]center dot 0.5H(2)O (dien = NH(CH2-CH2NH2)(2)), (NH4)(2)[Zn{O-2-B6O7(OH)(6)}(2) (H2O)(2)]center dot 2H(2)O and (1,3-pnH(2))(3)[(N-1-H3N{CH2}(3)NH2) Zn{O-3-B12O18(OH)(6)}](2)center dot 14H(2)O (1,3-pn = 1,3-diaminopropane)

AU - Altahan, Mohammed

AU - Beckett, Michael

AU - Coles, Simon J.

AU - Horton, Peter N.

PY - 2019/4

Y1 - 2019/4

N2 - Two zinc(II) hexaborate(2-) complexes, [Zn{3O-B6O7(OH)6}(3N-dien)].0.5H2O (dien = NH(CH2CH2NH2)2) (1) and (NH4)2[Zn{2O-B6O7(OH)6}2(H2O)2].2H2O (2), and a zinc(II) dodecaborate(6-) complex, (1,3-pnH2)3[(1N-H3N{CH2}3NH2)Zn{3O-B12O18(OH)6}]2.14H2O (1,3-pn = 1,3-diaminopropane) (3), have been synthesized and characterized by single-crystal XRD studies. The complexes crystallized, through self-assembly processes, from aqueous solutions containing 10:1 ratios of B(OH)3 and appropriate Zn(II) amine complex: [Zn(dien)2](OH)2, [Zn(NH3)4](OH)2, and [Zn(pn)3](OH)2. The hexaborate(2-) anions in 1 and 2 are coordinated to octahedral Zn(II) centres as tridentate (1) or bidentate ligands (2) and the dodecaborate(6-) ligand in 3 is tridentate to a tetrahedral Zn(II) centre.

AB - Two zinc(II) hexaborate(2-) complexes, [Zn{3O-B6O7(OH)6}(3N-dien)].0.5H2O (dien = NH(CH2CH2NH2)2) (1) and (NH4)2[Zn{2O-B6O7(OH)6}2(H2O)2].2H2O (2), and a zinc(II) dodecaborate(6-) complex, (1,3-pnH2)3[(1N-H3N{CH2}3NH2)Zn{3O-B12O18(OH)6}]2.14H2O (1,3-pn = 1,3-diaminopropane) (3), have been synthesized and characterized by single-crystal XRD studies. The complexes crystallized, through self-assembly processes, from aqueous solutions containing 10:1 ratios of B(OH)3 and appropriate Zn(II) amine complex: [Zn(dien)2](OH)2, [Zn(NH3)4](OH)2, and [Zn(pn)3](OH)2. The hexaborate(2-) anions in 1 and 2 are coordinated to octahedral Zn(II) centres as tridentate (1) or bidentate ligands (2) and the dodecaborate(6-) ligand in 3 is tridentate to a tetrahedral Zn(II) centre.

KW - X-ray structure

KW - dodecaborate(6-)

KW - hexaborate(2-)

KW - oxidoborate

KW - polyborate

KW - self-assembly

KW - zinc(II) complex

U2 - 10.3390/inorganics7040044

DO - 10.3390/inorganics7040044

M3 - Article

VL - 7

JO - Inorganics

JF - Inorganics

IS - 4

M1 - 44

ER -