Iodotris(triphenylphosphine)silver(I), [Ag(PPh3)3I]
Research output: Contribution to journal › Article › peer-review
Electronic versions
DOI
The geometry about the Ag atom in the title complex, C54H45AgIP3, is distorted tetrahedral with the Ag-I bond length 2.8660 (11) Å and Ag-P distances 2.5335 (14), 2.5589 (12) and 2.6814 (12) Å. The P-Ag-P/I angles show large variations [104.54 (3) to 116.10 (4)°] from the ideal tetrahedral value (109.45°). These distortions, as well as those around the P atoms in the three triphenylphosphine ligands, may be attributed to several intramolecular (H...I and H...C/H) short contacts.
| Original language | English |
|---|---|
| Pages (from-to) | 884-887 |
| Number of pages | 4 |
| Journal | Acta Crystallographica Section C Crystal Structure Communications |
| Volume | 52 |
| DOIs | |
| Publication status | Published - 1996 |