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Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts

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Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts. / Beckett, Michael; Coles, Simon; Horton, Peter N. et al.
In: European Journal of Inorganic Chemistry , Vol. 2017, No. 38-39, 2017, p. 4510-4518.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Beckett, M, Coles, S, Horton, PN & Jones, C 2017, 'Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts', European Journal of Inorganic Chemistry , vol. 2017, no. 38-39, pp. 4510-4518. https://doi.org/10.1002/ejic.201700551

APA

Beckett, M., Coles, S., Horton, P. N., & Jones, C. (2017). Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts. European Journal of Inorganic Chemistry , 2017(38-39), 4510-4518. https://doi.org/10.1002/ejic.201700551

CBE

Beckett M, Coles S, Horton PN, Jones C. 2017. Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts. European Journal of Inorganic Chemistry . 2017(38-39):4510-4518. https://doi.org/10.1002/ejic.201700551

MLA

Beckett, Michael et al. "Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts". European Journal of Inorganic Chemistry . 2017, 2017(38-39). 4510-4518. https://doi.org/10.1002/ejic.201700551

VancouverVancouver

Beckett M, Coles S, Horton PN, Jones C. Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts. European Journal of Inorganic Chemistry . 2017;2017(38-39):4510-4518. Epub 2017 Jul 31. doi: 10.1002/ejic.201700551

Author

Beckett, Michael ; Coles, Simon ; Horton, Peter N. et al. / Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts. In: European Journal of Inorganic Chemistry . 2017 ; Vol. 2017, No. 38-39. pp. 4510-4518.

RIS

TY - JOUR

T1 - Polyborate anions partnered with large non-metal cations: triborate(1-), pentaborate(1-), and heptaborate(2-) salts

AU - Beckett, Michael

AU - Coles, Simon

AU - Horton, Peter N.

AU - Jones, Charlotte

N1 - journal has rated this as a 'Very Important Paper'

PY - 2017

Y1 - 2017

N2 - New polyborate salts containing bulky non-metal cations have been prepared from either the free organic base or the [non-metal cation][OH] in methanolic aqueous solution: 1-adamantylammonium pentaborate [C10H18N][B5O6(OH)4] (1), 2-adamantylammonium pentaborate dihydrate [C10H18N][B5O6(OH)4].2H2O (2), N,N-dimethyl-1-adamantylammonium pentaborate.boric acid monohydrate [C12H22N][B5O6(OH)4].B(OH)3.H2O (3), N,N,N-trimethyl-1-adamantylammonium pentaborate trihydrate [C13H24N][B5O6(OH)4].3H2O (4), N,N,N-trimethyl-2-adamantylammonium pentaborate trihydrate [C13H24N][B5O6(OH)4].3H2O (5), dibenzylammonium pentaborate sesquihydrate [C14H16N][B5O6(OH)4].1.5H2O (6), bis(triphenylphosphine)iminium pentaborate sesquihydrate [C36H30NP2][B5O6(OH)4].1.5H2O (7), bis(triphenylphosphine)iminium triborate.2.5 hydrate [C36H30NP2][B3O3(OH)4].2.5H2O (8), 4,4’-bipiperidinium heptaborate dihydrate [C10H22N2][B7O9(OH)5].2H2O (9). All compounds were characterized by thermal (TGA/DSC), and spectroscopic analysis (NMR, IR). Compounds 3 - 5 and 9 have been characterized by single-crystal XRD studies. The waters of crystallization in 3 - 6 and the boric acid of crystallization in 3 play important structural roles in expanding the supramolecular pentaborate(1-) lattices to accommodate the bulkier cations.

AB - New polyborate salts containing bulky non-metal cations have been prepared from either the free organic base or the [non-metal cation][OH] in methanolic aqueous solution: 1-adamantylammonium pentaborate [C10H18N][B5O6(OH)4] (1), 2-adamantylammonium pentaborate dihydrate [C10H18N][B5O6(OH)4].2H2O (2), N,N-dimethyl-1-adamantylammonium pentaborate.boric acid monohydrate [C12H22N][B5O6(OH)4].B(OH)3.H2O (3), N,N,N-trimethyl-1-adamantylammonium pentaborate trihydrate [C13H24N][B5O6(OH)4].3H2O (4), N,N,N-trimethyl-2-adamantylammonium pentaborate trihydrate [C13H24N][B5O6(OH)4].3H2O (5), dibenzylammonium pentaborate sesquihydrate [C14H16N][B5O6(OH)4].1.5H2O (6), bis(triphenylphosphine)iminium pentaborate sesquihydrate [C36H30NP2][B5O6(OH)4].1.5H2O (7), bis(triphenylphosphine)iminium triborate.2.5 hydrate [C36H30NP2][B3O3(OH)4].2.5H2O (8), 4,4’-bipiperidinium heptaborate dihydrate [C10H22N2][B7O9(OH)5].2H2O (9). All compounds were characterized by thermal (TGA/DSC), and spectroscopic analysis (NMR, IR). Compounds 3 - 5 and 9 have been characterized by single-crystal XRD studies. The waters of crystallization in 3 - 6 and the boric acid of crystallization in 3 play important structural roles in expanding the supramolecular pentaborate(1-) lattices to accommodate the bulkier cations.

U2 - 10.1002/ejic.201700551

DO - 10.1002/ejic.201700551

M3 - Article

VL - 2017

SP - 4510

EP - 4518

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 38-39

ER -